Durable, transparent and superhydrophobic coating with temperature-controlled dual-scale roughness by self-assembled raspberry nanoparticles.

This study focuses on creating a superhydrophobic, durable, and exceptionally transparent coating with dual-scale roughness by naturally formed raspberry-like particles. This approach facilitates the management of surface roughness at both single and dual scales through variations in surface functionalization temperature. We illustrated that adjusting the temperature of organosilanes functionalization on the surface allows for various reactions, such as the direct grafting of metallic precursors or their polymerization on the surface, resulting in the formation of large raspberry-like particles.

Dextran-Coated Latex Nanoparticles via Photo-RAFT Mediated Polymerization Induced Self-Assembly.

Polysaccharide coated nanoparticles represent a promising class of environmentally friendly latex to replace those stabilized by small toxic molecular surfactants. We report here an in situ formulation of free-surfactant core/shell nanoparticles latex consisting of dextran-based diblock amphiphilic copolymers. The synthesis of copolymers and the immediate latex formulation were performed directly in water using a photo-initiated reversible addition fragmentation chain transfer-mediated polymerization induced self-assembly strategy.