N-alkyldinaphthocarbazoles, azaheptacenes, for solution-processed organic field-effect transistors.

Substituted N-alkyldinaphthocarbazoles were synthesized using a key double Diels-Alder reaction. The angular nature of the dinaphthocarbazole system allows for increased stability of the conjugated system relative to linear analogues. The N-alkyldinaphthocarbazoles were characterized by UV-vis absorption and fluorescence spectroscopy as well as cyclic voltammetry.