Nanocomposite strain sensors composed of compressed honeycomb-like reduced-graphene-oxide (RGO) foam embedded in polydimethylsiloxane are facilely fabricated via unidirectional freeze-drying and simple mechanical compression. The microstructural characteristics of the nanocomposites endow the sensors with excellent flexibility, high stretchability and sensing sensitivity, as well as anisotropic mechanical and sensing performance when stretched along directions vertical and parallel to the aligned RGO cell walls (defined as transverse and longitudinal directions, respectively). In particular, the compression of the aligned RGO foam into a thinner film results in more conductive pathways, greatly increasing the sensing sensitivity of the nanocomposite sensors.
View Article and Find Full Text PDFFlexible waterborne polyurethane (WPU)/silver nanowire (AgNW) nanocomposites with unidirectionally aligned micrometer-sized pores are fabricated using a facile freeze-drying process, and their dimensions, densities, and AgNW contents are easily controllable. The high-aspect-ratio AgNWs are well-dispersed in the nanocomposite cell walls, giving the nanocomposites good compression strength and excellent electrical conductivity even at very low densities. The large conductivity mismatch between the AgNWs and WPU also induces substantial interfacial polarization that benefits the absorption of electromagnetic (EM) waves, whereas the aligned cell walls promote multireflections of the waves in the porous architectures, further facilitating the absorption.
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