A glass composition using TeO-KTeO-NbO-BaF co-doped with ErO/HoO and ErO/YbO was successfully fabricated. Its thermal stability and physical parameters were studied, and luminescence spectroscopy of the fabricated glasses was conducted. The optical band gap, , decreased from 2.
View Article and Find Full Text PDFThis study investigates the synergistic effects of alginate@montmorillonite (Alg@Mt) hybrid microcapsules for enhancing water purification, focusing on improving the encapsulation of hydrophobic contaminants. Alg@Mt microcapsules were prepared through ionotropic gelation. Characterisation was performed using SEM-EDX, FTIR, XRD, and TGA.
View Article and Find Full Text PDFRecently, Cellulose microfibers (CMF) have garnered significant attention due to their renewability, biodegradability, and unique properties such as high aspect ratio, low density, high strength, stiffness, and distinctive optical properties. These characteristics have been highlighted in publications worldwide. However, the structure of CMF is difficult to access with solvents, limiting its dissolution in common organic solvents.
View Article and Find Full Text PDFThe thermal and optical properties of 60TeO-20KTeO-10WO-10NbO (in mol%) glasses doped with HoO, ErO, and TmO were explored in the present work. The thermal stability, refractive index n, extinction coefficient k, absorption coefficient α, and optical band gap of the glasses were evaluated. The UV-Vis-NIR absorption spectra, the Judd-Ofelt intensity parameter, the spectroscopic quality factor, and the emission and absorption cross-sections were calculated to investigate the effects of Er and Tm, respectively, on the band spectroscopic properties of Ho ions.
View Article and Find Full Text PDFTannin, after lignin, is one of the most abundant sources of natural aromatic biomolecules. It has been used and chemically modified during the past few decades to create novel biobased materials. This work intended to functionalize for the first time quebracho Tannin (T) through a simple phosphorylation process in a urea system.
View Article and Find Full Text PDFIn this work, chitin (CT) was isolated from shrimp shell waste (SSW) and was then phosphorylated using diammonium hydrogen phosphate (DAP) as a phosphorylating agent in the presence of urea. The prepared samples were characterized using Scanning Electron Microscopy (SEM) and EDX-element mapping, Fourier Transform Infrared Spectroscopy (ATR-FTIR), X-Ray Diffraction (XRD), Thermogravimetric Analysis (TGA/DTG), conductometric titration, Degree of Substitution (DS) and contact angle measurements. The results of characterization techniques reveal the successful extraction and phosphorylation of chitin.
View Article and Find Full Text PDFIntroduction: Pediatric end-stage renal disease is a rare but severe condition that causes numerous complications and impairs the quality of life of children. Kidney transplantation is the therapy of choice in pediatric end-stage renal disease.
Aim: Our study aimed to identify the predictive factors of renal graft failure after kidney transplantation in Tunisian children and young adults.
Introduction: There are three types of primary hyperoxaluria, with type 1 considered the most severe.
Aim: To analyze the clinical, genetic, and evolutionary characteristics of type 1 primary hyperoxaluria with pediatric onset.
Methods: This was a retrospective, descriptive study that included Tunisian children under the age of 18 at the time of diagnosis over a period of 25 years (January 1, 1996, to December 31, 2022).
Exp Clin Transplant
January 2024
Objectives: We aimed to identify risk factors and outcomes of delayed graft function in pediatric kidney transplant.
Materials And Methods: This retrospective study included all kidney transplant recipients ≤19 years old followed up in our department for a period of 34 years, from January 1989 to December 2022.
Results: We included 113 kidney transplant recipients.
Introduction: Acquisition of dosimetric knowledge by radiation therapy planners is a protracted and complex process. This study delves into the impact of empirical predictive models based on the knowledge-based planning (KBP) methodology, aimed at detecting suboptimal results and homogenizing and improving existing practices for prostate cancer. Moreover, the dosimetric effect of implementing these models into routine clinical practice was also assessed.
View Article and Find Full Text PDFIntroduction: Focal segmental glomerulosclerosis is a histopathological entity.
Aim: To analyze the epidemiological, clinical and histological profile of primary focal segmental glomerulosclerosis in children, as well as their prognostic factors.
Methods: This was a retrospective cross-sectional study over a period of 20 years (2001-2020), conducted in the Department of Pediatrics at Charles Nicolle Hospital in Tunis, which included children followed for primary focal segmental glomerulosclerosis.
Polyuria-polydipsia syndrome is a frequent symptom in pediatrics, primarily attributed to diabetes mellitus. In the context of diabetes insipidus, this syndrome can stem from central or nephrogenic factors. Sjögren's syndrome, an uncommon autoimmune disease in children, can affect multiple organs.
View Article and Find Full Text PDFAim: To identify the predictive factors for the occurrence of community-acquired urinary tract infections caused by Extended-Spectrum β-Lactamase-Producing Escherichia coli in children.
Methods: This was a single-center prospective observational study of children and young adults with community-acquired urinary tract infections caused by Extended-Spectrum β-Lactamase-Producing Escherichia coli. The study was conducted in the pediatric nephrology department in Charles Nicolle Hospital, Tunis, Tunisia from January 1st, 2019, to December 31, 2020.
The overwhelming concerns of water pollution, industrial discharges and environmental deterioration by various organic and inorganic substances, including dyes, heavy metals, pesticides, pharmaceuticals, and detergents, intrinsically drive the search for urgent and efficacious decontamination techniques. This review illustrates the various approaches to remediation, their fundamentals, characteristics and demerits. In this manner, the advantageous implementation of nature-based adsorbents has been outlined and discussed.
View Article and Find Full Text PDFNeuroblastoma is the most common extracranial solid tumor in children, often manifests in the retroperitoneal region. We present a case of a 3-year-old boy with no previous medical history, presented for abdominal distension. Physical examination revealed a distinct, mobile, solid mass situated in the left lumbar region.
View Article and Find Full Text PDFThis study aims to investigate the mechanical behavior of alginate-based simple and alginate@clay-based hybrid capsules under uniaxial compression using a Brookfield force machine. The effect of clay type and content on Young's modulus and nominal rupture stress of the capsules was investigated and characterized using Scanning Electron Microscopy (SEM), and Fourier Transform Infrared Spectroscopy (ATR-FTIR). Results showed that clay content improves the mechanical properties depending on its type.
View Article and Find Full Text PDFKey Clinical Message: Genetic counseling and genetic screening for hyperoxaluria should be recommended for children with urinary lithiasis for early management to avoid progression to oxalosis especially if there is a family history of lithiasis.
Unlabelled: Primary hyperoxaluria type 1 (PH1) is caused by a deficiency of the liver peroxisomal enzyme alanine-glyoxylate aminotransferase (AGT) resulting in overproduction of calcium oxalates. In its later stage, a systemic deposit of calcium oxalates is observed.
Introduction: Pleuropulmonary blastoma (PPB) is rare, representing 0.3 % of all pediatric cancers. PPB is classified into three subtypes and may progress from type I to types II and III, with a worse prognosis.
View Article and Find Full Text PDFHalophilic archaea are polyextremophiles with the ability to withstand fluctuations in salinity, high levels of ultraviolet radiation, and oxidative stress, allowing them to survive in a wide range of environments and making them an excellent model for astrobiological research. Natrinema altunense 4.1R is a halophilic archaeon isolated from the endorheic saline lake systems, Sebkhas, located in arid and semi-arid regions of Tunisia.
View Article and Find Full Text PDFSpontaneous hemothorax occurs in the absence of trauma or iatrogenic causes. Etiologies of spontaneous hemothorax in children include connective tissue disease, neoplasia and coagulopathy, which is associated with thromboembolic events. We present the case of a 10-year-old chronic hemodialysis patient with spontaneous hemothorax with a concurrent COVID-19 infection.
View Article and Find Full Text PDFObjective: To describe the clinical, biochemical and evolutive profile of monogenic urinary lithiasis in Tunisian children followed up in a reference service, during a 25 years period.
Methods: This was a single-center retrospective observational study of children with urolithiasis, conducted in the pediatric nephrology department in Charles Nicolle Hospital, Tunis, Tunisia over 25 years (January 1st, 1996 to December 31, 2020). Children≤18 of age with urolithiasis with or without nephrocalcinosis related to a monogenic disease were included in our study.