A new kind of silica nanotube with incorporated γ-Fe(2)O(3) nanoparticles has been successfully prepared through sol-gel processes. Hematite particles supported on carbon nanotubes served as templates for the fabrication of the magnetic silica nanotubes. The obtained nanostructures consisting of magnetic Fe(2)O(3) nanoparticles protected by a silica shell were fully characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), N(2) sorption and desorption, and magnetization studies.
View Article and Find Full Text PDFCarbon nanotubes possess interesting physicochemical properties which make them potentially usable in medicine. Single-walled carbon nanotubes and multi-walled carbon nanotubes, for example, may carry and deliver anticancer drugs, such as cisplatin. Magnetic nanoparticles, like iron filled MWCNT, can be used in hyperthermia therapy.
View Article and Find Full Text PDFColloids Surf B Biointerfaces
January 2012
The synthesis, characterization, and toxicity of graphene oxide and reduced graphene oxide are reported. Prior to the cytocompatibility tests the stability of the suspensions in a wide range of concentrations (3.125-100 μg/mL) of three different dispersants is studied.
View Article and Find Full Text PDFThe initial development of carbon nanotube synthesis revolved heavily around the use of 3d valence transition metals such as Fe, Ni, and Co. More recently, noble metals (e.g.
View Article and Find Full Text PDFA stimuli-responsive controlled-release delivery system based on carbon nanotubes is demonstrated. Through TEM, FTIR spectroscopic, and thermogravimetric analysis, functional groups have been successfully attached to the open ends of the tubes, thereby enabling functionalized silica spheres to preferentially attach to the ends. This, in essence, plugs the ends of the tube.
View Article and Find Full Text PDFJ Mater Sci Mater Med
April 2011
The paper presents a study on functionalisation of multi-walled carbon nanotubes in the area of lattice defects and an attempt to bind the nanotubes with pitavastatin. Carbon nanotubes were synthesised by alcohol-chemical vapour deposition in the presence of the catalyst Fe-Co/MgO. The nanotubes were purified and the product was subjected to chemical functionalisation.
View Article and Find Full Text PDFWe present in situ experimental observations of fullerenes seamlessly fusing to single-walled carbon nanotubes. The morphing-entry of a fullerene to the interior of a nanotube is also captured. The confined (1D) motion of the newly-encapsulated fullerene within its host attests to the actual change from the exterior to interior.
View Article and Find Full Text PDFMulti-walled carbon nanotubes from 8 to 63 nm in diameter and from 60 to 413 nm in length, were synthesized over nickel supported on a zeolite by the chemical vapor deposition of methane in the relatively low temperature range 400-550 degrees C. The carbon deposited was analyzed by x-ray powder diffraction, Raman spectroscopy, and scanning and transmission electron microscopy. The effects of the reaction temperature on the carbon nanotube formation and relative purity were evaluated.
View Article and Find Full Text PDFA detailed study on the influence of the substrate loading (relative to the catalyst content) and supply pressure of the feedstock on the diameter and distribution of the number of walls in carbon nanotubes in alcohol chemical vapor deposition (CVD) is presented. Here we show how one can modify the technique for the bulk formation of high quality desired nanotube types: single-walled, double-walled or multi-walled CNTs. The influence of the concentration of the catalysts with respect to the substrate concentration was examined to select the optimal conditions in terms of the sample quality.
View Article and Find Full Text PDFEvidence for modified electronic structure in double-walled carbon nanotubes with respect to their individual inner and outer constituent single-walled nanotubes is provided by scanning tunneling microscopy and spectroscopy experiments. The contribution originating from the inner tube to the local density of states of the double-walled system was identified in agreement with previous theoretical calculations. Consequently, the chiral index for the inner tube was extracted based on the additional van Hove singularities present in the experimental tunneling spectra.
View Article and Find Full Text PDFIn this letter, we show for the first time the use of metal oxides as catalysts in the synthesis of single-walled carbon nanotubes (SWCNTs) using laser ablation. Further, SWCNTs have been synthesized at low temperature (down to room temperature), where their nucleation cannot be explained via fullerene nucleation. The data point to a nucleation mechanism previously not identified, that places a stable oxidized ring as the root cause for the growth of SWCNTs.
View Article and Find Full Text PDFWe report the infrared (IR) response of bulk samples of multiwalled boron nitride nanotubes, produced by a substitution reaction from single walled carbon nanotubes, which is dominated by two characteristic BN-vibrations at 800 and 1372 cm-1.
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