This paper studies the chemical and mechanochemical preparation of glauconite with ammonium dihydrogen phosphate (ADP) nanocomposites with a ratio of 9:1 in the vol.% and wt.%, respectively.
View Article and Find Full Text PDFThe dark geometrical relaxation of sterically congested diarylcarbenes under matrix conditions was studied by ESR using bis(2,4,6-trichlorophenyl)carbene as a test molecule. The initial decrease of the parameter D has been found to proceed independently from the well-known expansion of the cental carbenic angle. The latter manifested by the reduction of the parameter E appears to be in correlation with the molecular mobility of the immediate surroundings probed by the reorientation of the primarily aligned test carbene.
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