Hidden imaging in thin polymer films with embedded fluorescent peptide nanodots.

Fluorescent (FL) encrypting nanostructures, such as quantum dots, carbon dots, organic dyes, lanthanide nanocrystals, DNA, and more, are effective tools for advanced applications in high-resolution hidden imaging. These applications include tracking, labeling, security printing, and anti-counterfeiting drug technology. In this work, what we believe to be a new FL encoding nanostructures has been proposed, which consists of recently discovered nanometer-scale peptide dots.

Amplified spontaneous emission and gain in highly concentrated Rhodamine-doped peptide derivative.

Bioinspired fluorescence, being widely explored for imaging purposes, faces challenges in delivering bright biocompatible sources. While quite a few techniques have been developed to reach this goal, encapsulation of high-quantum yield fluorescent dyes in natural biological forms suggest achieving superior light-emitting characteristics, approaching amplified spontaneous emission and even lasing. Here we compare gain capabilities of highly concentrated Rhodamine B solutions with a newly synthesized biocompatible peptide derivative hybrid polymer/peptide material, RhoB-PEG1300-F6, which contains the fluorescent covalently bound dye.

Light waveguiding in bioinspired peptide nanostructures.

Basic optical properties of bioinspired peptide nanostructures are deeply modified by thermally mediated refolding of peptide secondary structure from α-helical to β-sheet. This conformational transition is followed by the appearance in the β-sheet structures of a wideband optical absorption and fluorescence in the visible region. We demonstrate that a new biophotonic effect of optical waveguiding recently observed in peptide/protein nanoensembles is a structure-sensitive bimodal phenomenon.

Peptide Nanophotonics: From Optical Waveguiding to Precise Medicine and Multifunctional Biochips.

Optical waveguiding phenomena found in bioinspired chemically synthesized peptide nanostructures are a new paradigm which can revolutionize emerging fields of precise medicine and health monitoring. A unique combination of their intrinsic biocompatibility with remarkable multifunctional optical properties and developed nanotechnology of large peptide wafers makes them highly promising for new biomedical light therapy tools and implantable optical biochips. This Review highlights a new field of peptide nanophotonics.

Peptide Integrated Optics.

Bio-nanophotonics is a wide field in which advanced optical materials, biomedicine, fundamental optics, and nanotechnology are combined and result in the development of biomedical optical chips. Silk fibers or synthetic bioabsorbable polymers are the main light-guiding components. In this work, an advanced concept of integrated bio-optics is proposed, which is based on bioinspired peptide optical materials exhibiting wide optical transparency, nonlinear and electrooptical properties, and effective passive and active waveguiding.

Peptide Optical waveguides.

Small-scale optical devices, designed and fabricated onto one dielectric substrate, create integrated optical chip like their microelectronic analogues. These photonic circuits, based on diverse physical phenomena such as light-matter interaction, propagation of electromagnetic waves in a thin dielectric material, nonlinear and electro-optical effects, allow transmission, distribution, modulation, and processing of optical signals in optical communication systems, chemical and biological sensors, and more. The key component of these optical circuits providing both optical processing and photonic interconnections is light waveguides.

Linear and nonlinear optical waveguiding in bio-inspired peptide nanotubes.

Unique linear and nonlinear optical properties of bioinspired peptide nanostructures such as wideband transparency and high second-order nonlinear optical response, combined with elongated tubular shape of variable size and rapid self-assembly fabrication process, make them promising for diverse bio-nano-photonic applications. This new generation of nanomaterials of biological origin possess physical properties similar to those of biological structures. Here, we focus on new specific functionality of ultrashort peptide nanotubes to guide light at fundamental and second-harmonic generation (SHG) frequency in horizontal and vertical peptide nanotubes configurations.

Simulation and experimental investigation of optical transparency in gold island films.

Localized surface plasmons-polaritons represent collective behavior of free electrons confined to metal particles. This effect may be used for enhancing efficiency of solar cells and for other opto-electronic applications. Plasmon resonance strongly affects optical properties of ultra-thin, island-like, metal films.

Measuring nanolayer profiles of various materials by evanescent light technique.

The evanescent light photon extraction efficiency of insulator, semiconductor and conductor amorphous nanolayers deposited on glass waveguides was evaluated from Differential Evanescent Light Intensity measurements. The Differential Evanescent Light Intensity technique uses the evanescent field scattered by the deposited nanolayer, enabling nanometer thickness profiling due to the high inherent dark background contrast. The results show that the effective evanescent photon penetration depth increases from metal to semiconductor and then to insulating layers, establishing thus the effective photon-material interaction length for the various materials classes.

Compensation of Coulomb blocking and energy transfer in the current voltage characteristic of molecular conduction junctions.

We have studied the influence of both exciton effects and Coulomb repulsion on current in molecular nanojunctions. We show that dipolar energy-transfer interactions between the sites in the wire can at high voltage compensate Coulomb blocking for particular relationships between their values. Tuning this relationship may be achieved by using the effect of plasmonic nanostructure on dipolar energy-transfer interactions.

Ring-type plasmon resonance in metallic nanoshells.

A simple, approximate theoretical model of surface plasmon resonance in two-dimensional metal nanoshells is developed. The model is based on the concept of short-range surface plasmons propagating around closed circular metal nanotubes. In this model, the plasmon resonance in a metal nanotube is treated as a propagating, self-interfering plasmonic wave, in a ring-type resonance, at plasmonic wavelengths matching an integer fraction of the nanotube's effective circumference.

Light absorption enhancement in thin silicon film by embedded metallic nanoshells.

Computer simulation studies of absorption enhancement in a silicon (Si) substrate by nanoshell-related localized surface plasmon resonance (LSPR) based on a finite-difference time-domain analysis are presented. The results of these studies show significant enhancement of over 15x in the near-bandgap spectral region of Si, using 40 nm diameter, two-dimensional silver (Ag) nanoshells, simulating cylindrical nanoshell structure. The studies also indicate a clear advantage of the cylindrical nanoshell structure over that of a completely filled Ag-nanocylinders.

Experimental study of an ultrasmall pixel, one-dimensional liquid-crystal device.

A one-dimensional, ultrasmall pixel liquid-crystal (LC) device is experimentally demonstrated. The device has a one-dimensional array of ten 1 mm long, interdigitated, reflective gold electrodes on a glass substrate and a common transparent electrode on the opposite substrate. The interdigitated electrodes are 2 microm wide, separated by a 1 microm interelectrode gap.

Experimental study of phase-step broadening by fringing fields in a three-electrode liquid-crystal cell.

The fringing-field broadening of a phase-step profile and its dependence on the thickness of a liquid-crystal (LC) cell were studied in a simple, three-electrode LC cell structure consisting of two lateral electrodes biased with a differential voltage and a third, grounded, electrode placed on the opposite substrate. The results were compared both with an approximate analytical model developed earlier for a fringe-field-broadening kernel and with computer simulations. Good agreement between the experiment and the theoretical as well as the simulation results is shown.

Fringing-field effect in liquid-crystal beam-steering devices: an approximate analytical model.

An approximate analytical model was developed that links the fringing-field broadening of the phase profile of a liquid-crystal (LC) beam-steering device, and the resulting diffraction efficiency, to the physical parameters of the device including the cell thickness as well as the dielectric, optical, and geometrical constants of the device. The analysis includes a full solution of the Laplace equation for the LC device in which the broadening of the initial voltage profile into an effective voltage-drop profile, due to the fringing-field effect, is derived. It is shown that within the linear approximation used, the broadening of the phase profile is identical to the broadening of the effective voltage profile in the presence of the fringing field.

On the fringing-field effect in liquid-crystal beam-steering devices.

A detailed simulation of the fringing-field effect in liquid-crystal (LC)-based blazed-grating structures has been carried out. These studies are aimed at clarifying the relationship between the width of the fringing-field-broadened phase profile of the blazed grating and the LC cell thickness. This fringing-field broadening of the blazed grating's phase profile is shown to affect mostly the 2pi phase-step zone (fly-back zone) of the blazed grating.