Micromachines (Basel)
December 2022
Over the last several years, two-photon polymerization has been a popular fabrication approach for photonic crystals due to its high spatial resolution. One-dimensional photonic crystals with photonic bandgap reflectivities over 90% have been demonstrated for the infrared spectral range. With the success of these structures, methods which can provide tunability of the photonic bandgap are being explored.
View Article and Find Full Text PDFA polymer-based, one-dimensional photonic crystal exhibiting anisotropic responses was demonstrated in the terahertz frequency range. The photonic crystal was composed of alternating compact and low-density polymethacrylate layers. The low-density layers consisted of sub-wavelength sized columns, which were slanted 45° with respect to the substrate surface normal to achieve form-birefringence.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
November 2020
In-situ Optical Emission Spectroscopy (OES) combined with quantum chemical calculations was used as a powerful tool to find out the exited reactive species existing in plasma discharge during the process of lead sulfide chalcogenide materials deposition. Low temperature nonequilibrium RF (40.68 MHz) plasma at low pressure (0.
View Article and Find Full Text PDFSpecification and tolerancing of surfaces with mid-spatial frequency (MSF) errors are challenging and require new tools to augment simple surface statistics to better represent the structured characteristics of these errors. A novel surface specification method is developed by considering the structured and anisotropic nature of MSF errors and their impact on the modulation transfer function (MTF). The result is an intuitive plot of bandlimited RMS error values in polar coordinates which contains the surface error anisotropy information and enables an easy to understand acceptance criterion.
View Article and Find Full Text PDFThere are a variety of common situations in which specification of a one-dimensional modulation transfer function (MTF) or two orthogonal profiles of the 2D MTF are not adequate descriptions of the image quality performance of an optical system. These include systems with an asymmetric on-axis impulse response, systems with off-axis aberrations, systems with surfaces that include mid-spatial frequency errors, and freeform systems. In this paper, we develop the concept of the Minimum Modulation Curve (MMC).
View Article and Find Full Text PDFOne-dimensional (1D) photonic crystals (PCs) were fabricated by three-dimensional (3D) direct laser writing using a single polymer to obtain reflectance values approaching that of a gold reference in the near-infrared (near-IR) spectral range. The PCs are composed of alternating compact and low-density polymer layers that provide the necessary periodic variation of the refractive index. The low-density polymer layers are composed of subwavelength-sized pillars which simultaneously serve as a scaffold while also providing refractive index contrast to the adjacent compact polymer layers.
View Article and Find Full Text PDFIn this paper, we present a model for BRDF that can be developed from a limited set of experimentally observed data, and which then can be used for predictive purposes in scene-generation or sensor-performance applications. The model is physics based and can be as detailed as desired, depending on the scope of experimental data available. Basic input parameters required are the complex refractive index of the material, or the directional hemispherical reflectivity (DHR) for s- and p-polarized radiation.
View Article and Find Full Text PDFThree-dimensional direct laser writing via two-photon polymerization is used to fabricate anti-reflective structured surfaces (ARSSs) composed of subwavelength conicoid features optimized to operate over a wide bandwidth in the near-infrared range from 3700 cm to 6600 cm (2.7-1.52 μm).
View Article and Find Full Text PDFThree different size gold square loop structures were fabricated as arrays on ZnS over a ground plane and designed to have absorptive fundamental, second order, and third order resonances at a wavelength of 10.6 µm and 60° off-normal. The angular dependent far-field spectral absorptivity was investigated over the mid-infrared for each size loop array.
View Article and Find Full Text PDFWhen considering the pseudo-heterodyne mode for detection of the modulus and phase of the near field from scattering scanning near-field optical microscopy (s-SNOM) measurements, processing only the modulus of the signal may produce an undesired constraint in the accessible values of the phase of the near field. A two-dimensional analysis of the signal provided by the data acquisition system makes it possible to obtain phase maps over the whole [0, 2π) range. This requires post-processing of the data to select the best coordinate system in which to represent the data along the direction of maximum variance.
View Article and Find Full Text PDFMid-infrared scattering scanning near-field optical microscopy, in combination with far-field infrared spectroscopy, and simulations, was employed to investigate the effect of mutual-element coupling towards the edge of arrays of loop elements acting as frequency selective surfaces (FSSs). Two different square loop arrays on ZnS over a ground plane, resonant at 10.3 µm, were investigated.
View Article and Find Full Text PDFA metasurface consisting of an infinite array of square loops was designed for maximal absorptivity for s-polarized light at a wavelength of 10.6 µm and 60 degrees off-normal. We investigate the effects of array truncation in finite arrays of this design using far-field FTIR spectroscopy and scattering scanning near-field optical microscopy.
View Article and Find Full Text PDFOptical metamaterials have unique properties which result from geometric confinement of the optical conductivity. We developed a series of infrared metasurfaces based on an array of metallic square loop antennas. The far-field absorption spectrum can be designed with resonances across the infrared by scaling the geometric dimensions.
View Article and Find Full Text PDFFrequency-selective surfaces (FSS) are a class of metasurfaces with engineered reflectance, absorbance, and transmittance behavior. We study an array of metallic crossed dipole FSS elements in the infrared using interferometric scattering-type scanning near-field optical microscopy (s-SNOM). We resolve the dependence of the near-field phase on the dimensions of the elements and compare with numerical models.
View Article and Find Full Text PDFThe semimetal antimony, with a plasma frequency ~80 times less than that of gold, is potentially useful as a host for infrared surface polaritons (SPs). Relevant IR SP properties, including the frequency-dependent propagation length and penetration depths for fields into the media on either side of the interface, were determined from optical constants measured on optically-thick thermally-evaporated Sb films over the wavelength range 1 to 40 μm. Plasma and carrier relaxation frequencies were determined from Drude-model fits to these data.
View Article and Find Full Text PDFWe compare three technological approaches for quarter-wave retarders within the context of polarimetric-imaging applications in the long-wave infrared (LWIR) spectrum. Performance of a commercial cadmium sulfide (CdS) crystalline waveplate, a multilayer meanderline structure, and a silicon (Si) form-birefringent retarder are evaluated under conditions of 8-12 μm broadband radiation emerging from an F/1 focusing objective. Metrics used for this comparison are the spectrally dependent axial ratio, retardance, and polarization-averaged power transmittance, which are averaged over the angular range of interest.
View Article and Find Full Text PDFThe quality of the image produced by optical reflectarrays as a function of the F/#, polarization, and wavelength is analyzed in this paper. The results are expressed as monochromatic and polychromatic modulation transfer functions. They show that large aperture multilevel reflectarrays perform quite close to the diffraction-limited case.
View Article and Find Full Text PDFWe present a novel reflective quarter-wave plate comprised of subwavelength meanderline elements. The device is operational over the long-wave infrared (LWIR) spectrum, with significant spectral and angular bandwidths. Power reflection is approximately 70% over the majority of the LWIR.
View Article and Find Full Text PDFWe use split ring resonators (SRRs) at optical frequencies to study strong coupling between planar metamaterials and phonon vibrations in nanometer-scale dielectric layers. A series of SRR metamaterials were fabricated on a semiconductor wafer with a thin intervening SiO(2) dielectric layer. The dimensions of the SRRs were varied to tune the fundamental metamaterial resonance across the infrared (IR) active phonon band of SiO(2) at 130 meV (31 THz).
View Article and Find Full Text PDFThe degree of coherence of a partially coherent monochromatic optical field is measured with a dual-dipole phased-array antenna coupled to a metal-oxide-metal tunnel diode detector. For a two-element phased-array, the degree of coherence is a measure of the correlation of electric fields received by the antennas as a function of the element separation. To extract the coherence function from the measured antenna response, a calibration method is developed to remove propagation loss and device nonuniformity.
View Article and Find Full Text PDFA modeling procedure is demonstrated, which allows representation of polarization-resolved BRDF data using only four parameters: the real and imaginary parts of an effective refractive index with an added parameter taking grazing incidence absorption into account and an angular-scattering parameter determined from the BRDF measurement of a chosen angle of incidence, preferably close to normal incidence. These parameters allow accurate predictions of s- and p-polarized BRDF for a painted rough surface, over three decades of variation in BRDF magnitude. To characterize any particular surface of interest, the measurements required to determine these four parameters are the directional hemispherical reflectance (DHR) for s- and p-polarized input radiation and the BRDF at a selected angle of incidence.
View Article and Find Full Text PDFIn addition to the electric field E(r), the associated magnetic field H(r) and current density J(r) characterize any electromagnetic device, providing insight into antenna coupling and mutual impedance. We demonstrate the optical analogue of the radio frequency vector network analyzer implemented in interferometric homodyne scattering-type scanning near-field optical microscopy for obtaining E(r), H(r), and J(r). The approach is generally applicable and demonstrated for the case of a linear coupled-dipole antenna in the midinfrared spectral region.
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