Qualitative characterisation and identification of microplastics in a freshwater dam at Gauteng Province, South Africa, using pyrolysis-gas chromatography-time of flight-mass spectrometry (Py-GC-ToF-MS).

Pyrolysis GC-ToF-MS-based analytical study was employed in the identification of microplastics (MPs) in the freshwater of a dam Rietvlei (RTV) located at Gauteng Province, South Africa. These MPs extracted in five locations of the dam were found to contain five different plastic polymeric constituents including PE, PS, PA, PVC and PET along with phthalate esters and fatty acid (amides and esters) derivatives as additives. Based on the fragmented pyrolyzate products, the contribution of plastic polymers and additives was 74% and 26% respectively.

The Py - GC-TOF-MS analysis and characterization of microplastics (MPs) in a wastewater treatment plant in Gauteng Province, South Africa.

Wastewater treatment plants (WWTPs) in South Africa, like is the case for most WWTPs around the globe albeit capable of removing substantial quantities of microplastics (MPs) and in fact, the treatments become ineffective for those plastic particles less than 100 µm. As a consequence, the receiving water bodies in which the final effluent is discharged becomes highly polluted. The present research is devoted to the analysis of the pervasive MPs in wastewaters of the treatment plant located in the Gauteng Province, South Africa using Pyrolysis - GC-TOF-MS.

Characterization of plastic micro particles in the Atlantic Ocean seashore of Cape Town, South Africa and mass spectrometry analysis of pyrolyzate products.

The microplastic particles with 29 pyrolyzate compounds of marine water samples from the seashore locations in Cape Town, South Africa were analysed using Pyrolysis- GC-TOF-MS. The mass spectra data documented the presence of various chemical groups that include alkanes, alkenes, dienes, fatty acids and esters, biphenyl and benzene (along with derivatives). Out of 16 identified polymers in the study area, polythene (PE) was the dominant in six out of seven locations with 87.

Fluoride removal studies using virgin and Ti (IV)-modified Musa paradisiaca (plantain pseudo-stem) carbons.

The preparation of carbons in virgin and Ti-modified forms under controlled conditions at low temperature from plantain pseudo-stem (Musa paradisiaca) was achieved. These prepared carbons were characterized for instrumental studies such as BET, FTIR, XRD, SEM with EDS and TGA to understand the chemistry and modification. The determination of IEP and pH established the presence of positive surface sites on the virgin (VMPC) and Ti-modified (TiMPC) carbons to facilitate the sorption of fluoride.