Transport-Friendly Microstructure in SSC-MEA: Unveiling the SSC Ionomer-Based Membrane Electrode Assemblies for Enhanced Fuel Cell Performance.

The significant role of the cathodic binder in modulating mass transport within the catalyst layer (CL) of fuel cells is essential for optimizing cell performance. This investigation focuses on enhancing the membrane electrode assembly (MEA) through the utilization of a short-side-chain perfluoro-sulfonic acid (SSC-PFSA) ionomer as the cathode binder, referred to as SSC-MEA. This study meticulously visualizes the distinctive interpenetrating networks of ionomers and catalysts, and explicitly clarifies the triple-phase interface, unveiling the transport-friendly microstructure and transport mechanisms inherent in SSC-MEA.

Nonequilibrium Structure Diagram of Pendular Suspensions under Large-Amplitude Oscillatory Shear.

For pendular suspensions with particles in contact with immiscible secondary liquid bridges, the shear field significantly influences particle aggregates and networks. In this work, we study the structure of the pendular network and how the structure changes under large-amplitude-oscillatory shear. Using rheology and optical microscopy, we found unique network destruction followed by reconstruction with increasing strain.

A New Solid-like State for Liquid/Liquid/Particle Mixtures with Bicontinuous Morphology of Concentrated Emulsion and Concentrated Suspension.

Research in exploring the microstructures of the ternary liquid/liquid/particle mixture is still a challenging task due to the complex interface properties and compositions of each phase. In this work, we report a new kind of solid-like state for ternary mixtures after the addition of a surfactant, which has the bicontinuous morphology of two phases, that is, the concentrated emulsion and the concentrated noncolloidal suspension. The bicontinuous morphology was justified by optical microscopy and the unique two-step yielding behavior under large oscillatory shear flow, which has the yielding character of a noncolloidal suspension at smaller strain and that of a concentrated emulsion at larger strain.