Application and prospects of EMOFs in the fields of explosives and propellants.

Energetic Metal-Organic Framework (EMOF) compounds have gained significant attention in recent years as a hot research topic in the fields of explosives and propellants. This article provides an overview of the latest research progress of EMOFs in various areas, including heat-resistant explosives, burning rate catalysts and initiating explosives. It discusses the recent development trends of high-energy EMOFs, such as high-dimensional and solvent-free structural design, simplified and scalable synthesis conditions, environmentally friendly manufacturing processes with tunable structures, high-energy, low-sensitivity and multifunctional target products.

Unveiling the unprecedented catalytic capability of micro-sized Co-ZIF-L for the thermal decomposition of RDX by 2D-structure-induced mechanism reversal.

Developing MOF-based catalysts with superior catalytic properties for the thermal decomposition of cyclotrimethylenetrinitramine (RDX) is significant for the application of novel and efficient combustion catalysts oriented to RDX-based propellants with excellent combustion performance. Herein, micro-sized Co-ZIF-L with a star-like morphology (SL-Co-ZIF-L) was found to exhibit unprecedented catalytic capability for the decomposition of RDX, which can lower the decomposition temperature of RDX by 42.9 °C and boost the heat release by 50.

Progress of Artificial Intelligence in Drug Synthesis and Prospect of Its Application in Nitrification of Energetic Materials.

Artificial intelligence technology shows the advantages of improving efficiency, reducing costs, shortening time, reducing the number of staff on site and achieving precise operations, making impressive research progress in the fields of drug discovery and development, but there are few reports on application in energetic materials. This paper addresses the high safety risks in the current nitrification process of energetic materials, comprehensively analyses and summarizes the main safety risks and their control elements in the nitrification process, proposes possibilities and suggestions for using artificial intelligence technology to enhance the "essential safety" of the nitrification process in energetic materials, reviews the research progress of artificial intelligence in the field of drug synthesis, looks forward to the application prospects of artificial intelligence technology in the nitrification of energetic materials and provides support and guidance for the safe processing of nitrification in the propellants and explosives industry.

3D Electron-Rich ZIF-67 Coordination Compounds Based on 2-Methylimidazole: Synthesis, Characterization and Effect on Thermal Decomposition of RDX, HMX, CL-20, DAP-4 and AP.

ZIF-67 is a three-dimensional zeolite imidazole ester framework material with a porous rhombic dodecahedral structure, a large specific surface area and excellent thermal stability. In this paper, the catalytic effect of ZIF-67 on five kinds of energetic materials, including RDX, HMX, CL-20, AP and the new heat-resistant energetic compound DAP-4, was investigated. It was found that when the mass fraction of ZIF-67 was 2%, it showed excellent performance in catalyzing the said compounds.

Research progress of EMOFs-based burning rate catalysts for solid propellants.

Energetic Metal Organic Frameworks (EMOFs) have been a hotspot of research on solid propellants in recent years. In this paper, research on the application of EMOFs-based burning rate catalysts in solid propellants was reviewed and the development trend of these catalysts was explored. The catalysts analyzed included monometallic organic frameworks-based energetic burning rate catalysts, bimetallic multifunctional energetic burning rate catalysts, carbon-supported EMOFs burning rate catalysts, and catalysts that can be used in conjunction with EMOFs.

Synthesis and Properties of Thermally Self-Healing PET Based Linear Polyurethane Containing Diels-Alder Bonds.

A Diels-Alder (DA) bond containing poly(tetrahydrofuran)-co-(ethyleneoxide) (PET) based linear polyurethane (PET-DA-PU) was synthesized via a prepolymer process using PET as raw material, DA diol as chain extender agent, and toluene-2,4-diisocyanate (TDI) as coupling agent. The structure of PET-DA-PU was characterized by attenuated total reflectance-Fourier transform-infrared spectroscopy (ATR-FTIR), proton nuclear magnetic resonance spectrometry (H NMR) and carbon nuclear magnetic resonance spectrometry (C NMR). The thermal performance and self-healing behavior of PET-DA-PU were investigated by differential scanning calorimetry (DSC), polarized optical microscope, universal testing machine, scanning electron microscopy (SEM) and NMR, respectively.

Fabrication of CL-20/HMX Cocrystal@Melamine-Formaldehyde Resin Core-Shell Composites Featuring Enhanced Thermal and Safety Performance via In Situ Polymerization.

Safety concerns remain a bottleneck for the application of 2,4,6,8,10,12-hexanitro- 2,4,6,8,10,12-hexaazaisowurtzitane (CL-20)/1,3,5,7-tetranitro-1,3,5,7-tetrazacyclooctane (HMX) cocrystal. Melamine-formaldehyde (MF) resin was chosen to fabricate CL-20/HMX cocrystal-based core-shell composites (CH@MF composites) via a facile in situ polymerization method. The resulted CH@MF composites were comprehensively characterized, and a compact core-shell structure was confirmed.

Facile synthesis and superior properties of a nitrogen-rich energetic Zn-MOF with a 2D azide-bridged bilayer structure.

Exploring the facile synthesis of Pb-free energetic metal-organic frameworks (EMOFs) with both high nitrogen content and high thermostability is a significant but challenging task in the field of MOF-based green energetic materials. Herein, a new EMOF, [Zn(atz)(N)] (atz = 5-amino-1-tetrazole), has been synthesized by simply using a commercial ligand (atz) under mild conditions. A probable mechanism for the formation of azide groups in the product has been proposed, in which the fraction of C-N and N-N bonds in atz is the key.

Two-in-one strategy for fluorene-based spirocycles Pd(0)-catalyzed spiroannulation of -iodobiaryls with bromonaphthols.

Rapid assembly of fluorene-based spirocycles represents a highly significant but challenging task in organic synthesis. Reported herein is a novel Pd(0)-catalyzed [4+1] spiroannulation of simple -iodobiaryls with bromonaphthols for the one-step construction of [4,5]-spirofluorenes in high yields with excellent functional group tolerance. Noteworthily, these valuable fluorene-based coumarin skeletons can enrich the database of -coumarins and exhibit excellent spectroscopic properties.

Palladium-Catalyzed Intermolecular [4+1] Spiroannulation by C(sp )-H Activation and Naphthol Dearomatization.

A novel palladium-catalyzed [4+1] spiroannulation was developed by using a C(sp )-H activation/naphthol dearomatization approach. This bimolecular domino reaction of two aryl halides was realized through a sequence of cyclometallation-facilitated C(sp )-H activation, biaryl cross-coupling, and naphthol dearomatization, thus rendering the rapid assembly of a new class of spirocyclic molecules in good yields with broad functional-group tolerance. Preliminary mechanistic studies indicate that C-H cleavage is likely involved in the rate-determining step, and a five-membered palladacycle was identified as the key intermediate for the intermolecular coupling.