Advances in Cellulose-Based Hydrogels: Current Trends and Challenges.

This paper provides a solid foundation for understanding the synthesis, properties, and applications of cellulose-based gels. It effectively showcases the potential of these gels in diverse applications, particularly in biomedicine, and highlights key synthesis methods and properties. However, to push the field forward, future research should address the gaps in understanding the environmental impact, mechanical stability, and scalability of cellulose-based gels, while also considering how to overcome barriers to their industrial use.

The Impact of Biomass Composition Variability on the Char Features and Yields Resulted through Thermochemical Processes.

This paper explores the intricate relations between biomass polymeric composition, thermochemical conversion routes, char yields and features in order to advance the knowledge on biomass conversion processes and customize them to meet specific requirements. An exhaustive characterization has been performed for three types of biomasses: (i) spruce bark, a woody primary and secondary residue from forestry and wood processing; (ii) wheat straws-agricultural waste harvest from arable and permanent cropland; and (iii) vine shoots, a woody biomass resulting from vineyard waste. Chemical (proximate and ultimate analysis), biochemical, trace elements, and thermal analyses were performed.

Agriculture 4.0: Polymer Hydrogels as Delivery Agents of Active Ingredients.

The evolution from conventional to modern agricultural practices, characterized by Agriculture 4.0 principles such as the application of innovative materials, smart water, and nutrition management, addresses the present-day challenges of food supply. In this context, polymer hydrogels have become a promising material for enhancing agricultural productivity due to their ability to retain and then release water, which can help alleviate the need for frequent irrigation in dryland environments.

Cellulose-Based Metallogels-Part 3: Multifunctional Materials.

The incorporation of the metal phase into cellulose hydrogels, resulting in the formation of metallogels, greatly expands their application potential by introducing new functionalities and improving their performance in various fields. The unique antiviral, antibacterial, antifungal, and anticancer properties of metal and metal oxide nanoparticles (Ag, Au, Cu, CuO, ZnO, AlO, TiO, etc.), coupled with the biocompatibility of cellulose, allow the development of composite hydrogels with multifunctional therapeutic potential.

Cellulose-Based Metallogels-Part 2: Physico-Chemical Properties and Biological Stability.

Metallogels represent a class of composite materials in which a metal can be a part of the gel network as a coordinated ion, act as a cross-linker, or be incorporated as metal nanoparticles in the gel matrix. Cellulose is a natural polymer that has a set of beneficial ecological, economic, and other properties that make it sustainable: wide availability, renewability of raw materials, low-cost, biocompatibility, and biodegradability. That is why metallogels based on cellulose hydrogels and additionally enriched with new properties delivered by metals offer exciting opportunities for advanced biomaterials.

Cellulose-Based Metallogels-Part 1: Raw Materials and Preparation.

Metallogels are a class of materials produced by the complexation of polymer gels with metal ions that can form coordination bonds with the functional groups of the gel. Hydrogels with metal phases attract special attention due to the numerous possibilities for functionalization. Cellulose is preferable for the production of hydrogels from economic, ecological, physical, chemical, and biological points of view since it is inexpensive, renewable, versatile, non-toxic, reveals high mechanical and thermal stability, has a porous structure, an imposing number of reactive OH groups, and good biocompatibility.

Gels, Aerogels and Hydrogels: A Challenge for the Cellulose-Based Product Industries.

During recent decades, the interest in renewable, biodegradable, non-fossil materials has been exponentially increasing. Thus, cellulose and cellulose-derived products have been extensively considered for a wide variety of new potential uses. Due to the sustainability of cellulosic raw materials and their excellent properties, the use and modification of cellulose-based materials can be versatile in the material science and technology community.