In the present work, the potential application of a fabricated halloysite nanotubes-Ag-TiO (HNT-Ag-TiO) composite loaded with a binary surfactant mixture made up of lecithin and Tween 80 (LT80) in remediating oil spillages was examined. The as-prepared Ag-TiO that was used in the fabrication of the HNT-Ag-TiO-LT80 composite was characterized by X-ray diffraction, Raman spectroscopy, UV-vis and diffuse reflectance spectroscopy, CV analyses, and SEM-EDX. The synthesized composite was also characterized by thermogravimetric analysis, Fourier-transform infrared spectroscopy, and scanning electron microscopy-energy dispersive X-ray spectroscopy.
View Article and Find Full Text PDFThis work is a comparative study between Shea butter (SB) and treated distillate aromatic extract oil (TDAE) as plasticizers in the vulcanization of natural rubber (NR)- carbon black (CB) vulcanizates (-CB-S-NR-). The plasticized -CB-S-NR- composites extended scorch (Ts2) and optimum (T90) curing times. The delays in crosslinking reaction were suspected to be due to the increased viscosity (ML) and insulation of the reacting species (NR, CB, Sulfur and other curing aids) by the films of plasticizers.
View Article and Find Full Text PDFThis study examined the sensitivity of single-walled (5,5) aluminium nitride nanotubes ((5,5) AlNNTs) to carbon monoxide (CO) and carbon dioxide (CO) gas molecules by performing DFT calculations using a hybrid functional, specifically, B3LYP (Becke's three-parameter, Lee-Yang-Parr) exchange-correlation functional at a 6-31G* basis set. This research investigates the adsorption behavior of CO and CO molecules on pristine and silicon-doped aluminum nitride nanotubes (AlNNTs) and examines their implications for sensor applications. The study assesses each system's adsorption energy, sensing potential, and recovery time to gain insights into their binding strength and practical viability.
View Article and Find Full Text PDFIn recent years, polyelectrolyte-incorporated functional materials have emerged as novel adsorbents for effective remediation of pollutants in water and wastewater. Polyelectrolytes (PEs) are a special class of polymers with long chains of repeating charged moieties. Polyelectrolyte complexes (PECs) are obtained by mixing aqueous solutions of oppositely charged PEs.
View Article and Find Full Text PDFEthylene-propylene grafted-maleic anhydride (EPR-g-MA) and a pure maleic anhydride (MA) were separately used to compound carboxylated acrylonitrile butadiene-rubber (XNBR) together with reduced graphene oxide (G) to form nanocomposites, by using melt compounding technique. The G-sheets in the presence of MA (GA samples) or EPR-g-MA (GB samples) generally increased the physico-mechanical properties including; crosslinking density, tensile strength and thermal degradation resistance etc., when compared with sample without MA or EPR-g-MA (GAO) and the virgin matrix.
View Article and Find Full Text PDFPlastic materials have contributed to the release of environmentally relevant particulate plastics which can be found almost everywhere and may be present in drinking water. Human exposure to these materials is diverse and our understanding of their internalization in the human body is incipient. This review discusses the state of knowledge of particulate plastics exposure in drinking water and the potential risks of adverse health in the human body.
View Article and Find Full Text PDFThe present research estimated the impact of storage on the microbial quality of high-density polyethylene drinking water. Samples were taken from two popular companies in Greater Accra using a two-sided exact test in SAS JMP to estimate the sample size. The samples were stored across three temperature profiles at 8 °C, 30 °C (average room temperature), and 40 °C (average outdoor temperature) for 28 days.
View Article and Find Full Text PDFHigh-Density Polyethylene (HDPE)-packaged water is a popular choice for urban potable water across Africa. However, the sources and fate of priority chemical contaminants have not been adequately reported. The present study seeks to determine the effect of storage and labelling on the levels of phthalates - dimethyl phthalate (DMP), diethyl phthalate (DEP), dibutyl phthalate (DBP), benzyl butyl phthalate (BBP) and di(2-hexylethyl) phthalate (DEHP) - in HDPE packaged water.
View Article and Find Full Text PDFDespite the fact that online gambling is increasing among students in low- and middle-income countries, studies on the reasons and attitudes of university students toward gambling and its associated social, economic, and academic implications on their lives have not been adequately explored in the Ghanaian setting. This study employed an exploratory research design to investigate the reasons and attitudes of students toward online gambling and how online gambling has affected their social, economic, and academic lives on campus. An interview guide was used in soliciting data from fifteen participants.
View Article and Find Full Text PDFPlastic packaged water is the drinking water of choice for urban populations across Africa but its quality remains questionable in most developing countries. Six hundred (600) packages, consisting of sachet and bottled water, were sampled from two high-end companies in Accra (Ghana) and stored through their shelf lives under an average room temperature of 30 °C. The samples were tested for physicochemical quality and the presence of bacteria and phthalate esters at 2 × 3 periods, where n is the sampled batch number.
View Article and Find Full Text PDFBackground: Inter-regional trends of visual loss in most developing countries remain largely unknown. We compared the causes of childhood blindness among children attending blind schools in the northern (one school) and southern (two schools) regions of Ghana and assessed their need for spectacles and low-vision devices.
Methods: Using a standardised methodology, children were examined by an ophthalmologist and optometrists in each location.
The release of water soluble dyes into the environment is an utmost concern in many countries. This paper presents the effects of AgCO-halloysite composites on the efficient removal of water soluble dyes. In this study, NaHCO solution was added dropwisely to halloysite nanotubes (HNTs) dispersed in aqueous AgNO to form AgCO-HNTs composite.
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