Objectives: To develop and externally validate an MRI-based diagnostic model for microvascular invasion (MVI) or Edmondson-Steiner G3/4 (i.e., high-risk histopathology) in solitary BCLC 0/A hepatocellular carcinoma (HCC) ≤ 5 cm and to assess its performance in predicting adjuvant therapy benefits.
View Article and Find Full Text PDFChem Commun (Camb)
December 2024
Here, the clever design of forming an ohmic contact between SnS and MXene can regulate interfacial electron transport through Ti-O-Sn chemical bonds. This fast directional charge transport kinetics is attributed to the built-in electric field formed by the ohmic contact. As expected, the photoreduction CO activity of the optimized SSTC-5 catalyst is 10.
View Article and Find Full Text PDFObjectives: This study aims to analyze the magnetic resonance imaging (MRI) change patterns of viable hepatocellular carcinomas (HCCs) following the initial transarterial chemoembolization (TACE).
Methods: A retrospective analysis of HCC patients' initial TACE from February 2015 to October 2022 across three centers and a clinical trial (NCT03113955) was conducted. The viability of residual HCCs at one and six months after TACE was evaluated using the LI-RADS Treatment Response Algorithm (LR-TRA) v2024.
LI-RADS Treatment Response Algorithm (TRA) version 2024 (v2024) introduced separate algorithms for detecting hepatocellular carcinoma (HCC) viability after radiation and nonradiation locoregional therapies (LRT). The nonradiation algorithm incorporated MRI-based ancillary features to optionally upgrade lesions from LR-TR Equivocal to LR-TR Viable. To compare the diagnostic performance of LI-RADS Nonradiation TRA v2024 with LI-RADS TRA version 2017 (v2017) and modified RECIST (mRECIST) for evaluating HCC response to LRT on MRI, with attention to the impact of ancillary features.
View Article and Find Full Text PDFCrafting semiconducting heterojunctions represents an effective route to enhance photocatalysis by improving interfacial charge separation and transport. However, lattice mismatch (δ) between different semiconductors can significantly hinder charge dynamics. Here, meticulous lattice tailoring is reported to create a covalent heterointerface with a built-in electric field (BIEF), imparting markedly improved hydrogen peroxide (HO) photosynthesis.
View Article and Find Full Text PDFArtificial photosynthesis for hydrogen peroxide (HO) presents a sustainable and environmentally friendly approach to generate clean fuel and chemicals. However, the catalytic activity is hindered by challenges such as severe charge recombination, insufficient active sites, and poor selectivity. Here, a robust strategy is proposed to regulate the electronic structure of catalyst by the collaborative effect of defect engineering and dopant.
View Article and Find Full Text PDFImmobilizing Fe-based nanoparticles on electron-rich biochar has becoming an attractive heterogeneous Fenton-like catalysts (Fe/BC) for wastewater decontamination. However, the insufficient graphitization of biochar causing low electron transfer and by slow HO activation limited its application. Herein, we firstly constructed FeS/biochar composite through all-solid molten salt method (Fe/MSBCs), which can provide strong polarization force and liquid reaction environment to improve carbonization.
View Article and Find Full Text PDFTo investigate the long-term effects of 2 commonly used low-osmolar contrast media, iohexol and iopromide, on renal function and survival in patients who underwent coronary angiography. A total of 14,141 cardiology patients from 2006 to 2013 were recruited, of whom 1,793 patients (679 patients on iohexol and 1,114 on iopromide) were evaluated for long-term renal impairment and 5,410 patients (1,679 patients on iohexol and 3,731 on iopromide) were admitted for survival analyses spanning as long as 15 years. Univariate and multivariate logistic regression were used to explore the risk factors for long-term renal impairment.
View Article and Find Full Text PDFModulation of the nanozyme's catalytic activity is crucial for its real applications in detecting target analytes. Herein, we fabricated the nanocomposite (NSC/CoNiS) of N, S co-doped carbon and CoNiS by a facile sol-gel approach. Compared to NSC/NiS, NSC/CoNiS with bimetallic active sites displayed better enzyme-mimetic activity.
View Article and Find Full Text PDFHepatocellular carcinoma (HCC) is the fifth most common malignancy and the third leading cause of cancer-related death worldwide. HCC exhibits strong inter-tumor heterogeneity, with different biological characteristics closely associated with prognosis. In addition, patients with HCC often distribute at different stages and require diverse treatment options at each stage.
View Article and Find Full Text PDFCobalt (Co) and oxides are the most common catalysts for activating peroxymonosulfate (PMS). However, practical applications of Co-based PMS-advanced oxidation processes are difficult to realize the degradation of the targeted pollutants due to poor yield of reactive oxygen species (ROS) and inaccessible active sites. Here, we designed 3D oxygen vacancy-rich (V-rich) variable Co species@carbon foam (CoO@CF) via coupling solvent-free and pyrolysis strategies for degrading tetracycline by PMS activation.
View Article and Find Full Text PDFPhotocatalytic hydrogen peroxide (HO) production will become a burgeoning strategy for solar energy utilization by selective oxygen reduction reaction (ORR). Polymeric carbon nitride (PCN) shows relatively high two-electron ORR selectivity for HO production but still limited low HO production efficiency due to slow exciton dissociation. Herein, we constructed a heptazine/triazine layer stacked carbon nitride heterojunction with fluorine/potassium (F/K) dual sites (FKHTCN).
View Article and Find Full Text PDFThe enhancement of the self-cleaning ability of photocatalytic membranes and their degradation efficiency over tetracycline (TC) still remains a challenge. In this study, an alternative silver vanadate quantum dots (AgVO QDs) doped reduced graphene oxide (RGO) and graphitic carbon nitride (CN) nanocomposites modified polyvinylidene fluoride (PVDF) membrane (AgVO/RGO/CN-PVDF) was successfully fabricated to enhance the photocatalytic activity. The AgVO/RGO/CN nanocomposites were functioned as the active component for the photocatalytic membrane.
View Article and Find Full Text PDFPhotocatalytic materials can be used as self-cleaning functional materials to alleviate the irreversible fouling of ultrafiltration membranes. In this work, the small size g-CN/BiMoO (SCB) blended polysulfone (PSF) ultrafiltration membranes was fabricated by hydrothermal and phase inversion methods. As a functional filler of ultrafiltration membranes, the small size g-CN nanosheet decorated on the surface of BiMoO can enhance the photocatalytic performance for bovine serum albumin (BSA) degradation, and remove irreversible fouling under visible light irradiation.
View Article and Find Full Text PDFDesigning photocatalytic membranes with excellent photocatalytic and self-cleaning ability based on the synergistic effect between the crystal structure of membrane matrix and photocatalyst is highly desirable. Herein, Z-scheme 2D/3D g-CN/BiOI heterojunction blended in beta-phase polyvinylidene fluoride membrane (β-phase PVDF) was prepared via solvent crystallization and phase inversion technique. As expected, the designed g-CN/BiOI/β-phase PVDF photocatalytic membranes (CN/BI/β-phase PVDF PMs) achieved exceptional photocatalytic degradation efficiency for tetracycline (94.
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