Synthesis of Silicon and Germanium Oxide Nanostructures via Photonic Curing; a Facile Approach to Scale Up Fabrication.

Silicon and Germanium oxide (SiO and GeO) nanostructures are promising materials for energy storage applications due to their potentially high energy density, large lithiation capacity (~10X carbon), low toxicity, low cost, and high thermal stability. This work reports a unique approach to achieving controlled synthesis of SiO and GeO nanostructures via photonic curing. Unlike conventional methods like rapid thermal annealing, quenching during pulsed photonic curing occurs rapidly (sub-millisecond), allowing the trapping of metastable states to form unique phases and nanostructures.

Nanoparticle-Polymer Surface Functionalizations for Capacitive Energy Storage: Experimental Comparison to First Principles Simulations.

Dielectric capacitors present many advantages for large-scale energy storage, but they presently require higher energy density. We demonstrate novel high energy density polymer-nanoparticle composite capacitors utilizing thiol-ene click chemistry surface groups to bond the nanoparticles covalently to the polymer matrix. Interfacial effects in composites cannot be observed directly, and in our previous work, we examined the nanoparticle-polymer interface in silico.

Ultra-long cycle life and binder-free manganese-cobalt oxide supercapacitor electrodes through photonic nanostructuring.

We report a novel photonic processing technique as a next-generation cost-effective technique to instantaneously synthesize nanostructured manganese-cobalt mixed oxide reduced graphitic oxide (Mn-Co-rGO) for supercapacitor electrodes in energy storage applications. The active material was prepared directly on highly conductive Pt-Si substrate, eliminating the need for a binder. Surface morphological analysis showed that the as-prepared electrodes have a highly porous and resilient nanostructure that facilitates the ion/electron movement during faradaic redox reactions and buffers the volume changes during charge-discharge processes, leading to the improved structural integrity of the electrode.

Nanostructured manganese oxides electrode with ultra-long lifetime for electrochemical capacitors.

We describe the instantaneous fabrication of a highly porous three-dimensional (3D) nanostructured manganese oxides-reduced graphitic oxide (MnO -rGO) electrode by using a pulse-photonic processing technique. Such nanostructures facilitate the movement of ions/electrons and offer an extremely high surface area for the electrode/electrolyte interaction. The electrochemical performance was investigated by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS) with 1 M KOH as the electrolyte.