Lithium-ion batteries (LIBs) are promising secondary batteries that are widely used in portable electronic devices, electric vehicles and smart grids. The design and synthesis of high-performance electrode materials play a crucial role in achieving lithium-ion batteries with high energy density, prolonged cycle life, and superior safety. CoO has attracted significant attention as a negative electrode material for lithium-ion batteries due to its high theoretical capacity and abundant resources.
View Article and Find Full Text PDFJ Tradit Complement Med
November 2023
Objective: Baicalin, which is a key bioactive constituent obtained from , has been utilized in traditional Chinese medicine for many centuries. Although it has been reported that Baicalin (BA) can inhibit the replication of the Hepatitis B virus (HBV), the exact mechanism behind this process remains unclear. Interferon-stimulated genes (ISGs) are crucial in the process of antiviral defense.
View Article and Find Full Text PDFThe sluggish four-electron oxygen evolving reaction is one of the key limitations of photoelectrochemical water decomposition. Optimizing the binding of active sites to oxygen in water and promoting the conversion of *O to *OOH are the key to enhancing oxygen evolution reaction. In this work, W-doped Cu V O (CVO) constructs corner-sharing tetrahedrally coordinated W-V dual active sites to induce the generation of electron deficiency active centers, promote the adsorption of ─OH, and accelerate the transformation of *O to *OOH for water splitting.
View Article and Find Full Text PDFHepatitis B virus (HBV) infection in humans and its associated diseases are long-standing problems. HBV can produce a large number of non-self-molecules during its life cycle, which acts as targets for innate immune recognition and initiation. Among these, interferon and its large number of downstream interferon-stimulated gene molecules are important early antiviral factors.
View Article and Find Full Text PDFHepatitis B virus (HBV)-related diseases are among the major diseases that affect millions of people worldwide. These diseases are difficult to eradicate and thus pose a serious global health challenge. There is an urgent need to understand the cross talk mechanism between HBV and the host.
View Article and Find Full Text PDFMetal oxide materials show promise for application in photoelectrocatalytic conversion due to their inherent advantages involving positive reactive surface, improved light absorption capability, efficient charge separation yield, and fast charge transport channels. The unique electrical and optical properties of metal oxide based photoelectrodes have a great effect on their performance in solar cells, photoelectrocatalysis, and photocatalysis. It has been reported that the presence of defects on grain boundaries, oxygen vacancy, doping strategy, and heterojunction play a vital role in both the efficiency and durability of their photoelectric application.
View Article and Find Full Text PDFSimplified perovskite solar cells (PSCs) were fabricated with the perovskite layer sandwiched and encapsulated between carbon-based electron transport layer (ETL) and counter electrode (CE) by a fully blade-coated process. A self-assembled monolayer of amphiphilic silane (AS) molecules on transparent conducting oxide (TCO) substrate appeals to the fullerene ETL deposition and preserves its integrity against the solvent damage. The AS serves as a "molecular glue" to strengthen the adhesion toughness at the TCO/ETL interface via robust chemical interaction and bonding, facilitating the interfacial charge extraction, increasing PCEs by 77 % and reducing hysteresis.
View Article and Find Full Text PDFOwing to its broad-spectrum antivirus activities, interferon (IFN) is an important alternative agent for use in the treatment of hepatitis B virus (HBV)-infected patients; however, the mechanism involved in the inhibition of HBV infection and replication by IFN remains unclear. We previously reported that the induction of TRIM5γ is important in the IFN treatment of HBV patients as it promotes the degradation of the HBx protein, while the manner in which TRIM5γ is induced by IFN and how TRIM5γ interacts with HBx remain unestablished until date. Our present findings confirmed the TRIM5γ-HBx-DDB1 interactions in the HBV-infected Primary human hepatocytes (PHH), and we further found that STAT3, and not STAT1, was responsible for the induction of TRIM5γ upon IFN stimulation and that the zinc binding site His123 on the BBOX domain was a decisive site in the interaction between TRIM5γ BBOX and HBx.
View Article and Find Full Text PDFClin Appl Thromb Hemost
September 2020
Deep vein thrombosis (DVT) is prevalent in patients with coronavirus disease 2019 (COVID-19). However, the risk factors and incidence rate of DVT remains elusive. Here, we aimed to assess the incidence rate and risk factors of DVT.
View Article and Find Full Text PDFIn this paper a new electrochemical DNA biosensor was prepared by using graphene (GR) and nickel oxide (NiO) nanocomposite modified carbon ionic liquid electrode (CILE) as the substrate electrode. GR and NiO nanoparticles were electrodeposited on the CILE surface step-by-step to get the nanocomposite. Due to the strong affinity of NiO with phosphate groups of ssDNA, oligonucleotide probe with a terminal 5'-phosphate group could be attached on the surface of NiO/GR/CILE, which could further hybridize with the target ssDNA sequence.
View Article and Find Full Text PDFIn this paper a graphene (GR) and copper sulfide (CuS) nanocomposite was synthesized by hydrothermal method and used for the electrode modification with a N-butylpyridinium hexafluorophosphate based carbon ionic liquid electrode (CILE) as the substrate electrode. Hemoglobin (Hb) was immobilized on the modified electrode to get a biocompatible sensing platform. UV-vis absorption spectroscopic results confirmed that Hb retained its native secondary structure in the composite.
View Article and Find Full Text PDFThe diffusion coefficients of n-alkanes (from CH4 to C14H30) in near critical and supercritical carbon dioxide at infinite dilution have been studied by molecular dynamics simulation. The simulation results agree well with experiment, which suggests that the simulation method is a powerful tool to obtain diffusion coefficients of solutes in fluids at high pressures. The local structures of such fluids are further investigated by calculating radial distribution functions and coordination numbers.
View Article and Find Full Text PDFMater Sci Eng C Mater Biol Appl
May 2013
In this paper a platinum (Pt) nanoparticle decorated graphene (GR) nanosheet was synthesized and used for the investigation on direct electrochemistry of myoglobin (Mb). By integrating GR-Pt nanocomposite with Mb on the surface of carbon ionic liquid electrode (CILE), a new electrochemical biosensor was fabricated. UV-Vis absorption and FT-IR spectra indicated that Mb remained its native structure in the nanocomposite film.
View Article and Find Full Text PDFHierarchical anatase TiO(2) nano-architecture arrays consisting of long TiO(2) nanowire trunk and numerous short TiO(2) nanorod branches on transparent conductive fluorine-doped tin oxide glass are successfully synthesized for the first time through a facile one-step hydrothermal route without any surfactant and template. Dye-sensitized solar cells based on the hierarchical anatase TiO(2) nano-architecture array photoelectrode of 18 μm in length shows a power conversion efficiency of 7.34% because of its higher specific surface area for adsorbing more dye molecules and superior light scattering capacity for boosting the light-harvesting efficiency.
View Article and Find Full Text PDFIn this paper an ionic liquid 1-hexylpyridinium hexafluorophosphate based carbon ionic liquid electrode (CILE) was fabricated and used as the basal electrode, which was further modified by graphene (GR) and ZrO2 nanoparticle with chitosan (CTS) film to immobilize the nanocomposite. The modified electrode was denoted as CTS-GR-ZrO2/CILE and further used for the simultaneous detection of adenosine and guanosine. Electrochemical performances of the modified electrode were greatly enhanced due to the presence of GR-ZrO2 nanocomposite, and the direct electro-oxidation behaviors of adenosine and guanosine were carefully investigated.
View Article and Find Full Text PDFA novel hierarchical TiO(2) flower consisting of anatase TiO(2) nanotubes on a Ti foil substrate has been prepared via a mild hydrothermal reaction of TiO(2) nanoparticles/Ti foil. The photovoltaic performance of DSSC based on hierarchical TiO(2) flowers/Ti (7.2%) is much higher than that of TiO(2) nanoparticle/Ti (6.
View Article and Find Full Text PDFLow-cost transparent counter electrodes (CEs) for efficient dye-sensitized solar cells (DSSCs) are prepared by using nanohybrids of carbon nanotube (CNT)-supported platinum nanoparticles as highly active catalysts. The nanohybrids, synthesized by an ionic-liquid-assisted sonochemical method, are directly deposited on either rigid glass or flexible plastic substrates by a facile electrospray method for operation as CEs. Their electrochemical performances are examined by cyclic voltammetry, current density-voltage characteristics, and electrochemical impedance spectroscopy (EIS) measurements.
View Article and Find Full Text PDFOne-dimensional and quasi-one-dimensional semiconductor nanostructures are desirable for dye-sensitized solar cells (DSSCs), since they can provide direct pathways for the rapid collection of photogenerated electrons, which could improve the photovoltaic performance of the device. Quasi-1D single-crystalline anatase TiO(2) nanostructures have been successfully prepared on transparent, conductive fluorine-doped tin oxide (FTO) glass with a growth direction of [101] through a facile hydrothermal approach. The influences of the initial titanium n-butoxide (TBT) concentration, hydrothermal reaction temperature, and time on the length of quasi-1D anatase TiO(2) nanostructures and on the photovoltaic performance of DSSCs have been investigated in detail.
View Article and Find Full Text PDFHierarchical ZnO hollow spheres (400-500 nm in diameter) consisting of ZnO nanoparticles with a diameter of approximately 15 nm have been successfully prepared by a facile and rapid sonochemical process. The formation of hierarchical ZnO hollow spheres is attributed to the oriented attachment and subsequent Ostwald ripening process according to time-dependent experiments. The as-prepared ZnO hollow spheres are used as a photoanode in dye-sensitized solar cells and exhibit a highly efficient power conversion efficiency of 4.
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