2D-on-2D Al-Doped NiCo LDH Nanosheet Arrays for Fabricating High-Energy-Density, Wide Voltage Window, and Ultralong-Lifespan Supercapacitors.

Battery-type electrode materials with high capacity, wide potential windows, and good cyclic stability are crucial to breaking through energy storage limitations and achieving high energy density. Herein, a novel 2D-on-2D Al-doped NiCo layered double hydroxide (NiCoAl LDH) nanosheet arrays with high-mass-loading are grown on a carbon cloth (CC) substrate via a two-step hydro/solvothermal deposition strategy, and the effect of Al doping is employed to modify the deposition behavior, hierarchical morphology, phase stability, and multi-metallic synergistic effect. The optimized NiCoAl LDH electrode exhibits capacities of 5.

Regulating the Electronic Structure of Bismuth Nanosheets by Titanium Doping to Boost CO Electroreduction and Zn-CO Batteries.

The electrochemical carbon dioxide reduction reaction (E-CO RR) to formate is a promising strategy for mitigating greenhouse gas emissions and addressing the global energy crisis. Developing low-cost and environmentally friendly electrocatalysts with high selectivity and industrial current densities for formate production is an ideal but challenging goal in the field of electrocatalysis. Herein, novel titanium-doped bismuth nanosheets (TiBi NSs) with enhanced E-CO RR performance are synthesized through one-step electrochemical reduction of bismuth titanate (Bi Ti O ).

Hydrogen-bond induced and hetero coupling dual effects in N-doped carbon coated CrN/Ni nanosheets for efficient alkaline freshwater/seawater hydrogen evolution.

Developing efficient and robust non-precious-metal-based hydrogen evolution reaction (HER) catalysts is highly desirable but remains quite challenging for alkaline freshwater/seawater electrolysis. In the present study, we report a theory-guided design and synthesis of a nickel foam (NF) supported N-doped carbon-coated (NC) nickel (Ni)/chromium nitride (CrN) nanosheets (NC@CrN/Ni) as a highly active and durable electrocatalyst. Our theoretical calculation firstly reveals that CrN/Ni heterostructure can greatly promote the HO dissociation via hydrogen-bond induced effect, and the N site can be optimized by hetero coupling to achieve a facile hydrogen associative desorption, thereby significantly boosting alkaline HER.

Restrictive Regulation of Ionic Liquid Quaternary Ammonium Salt in SBA-15 Pore Channel for Efficient Carbon Dioxide Conversion.

Herein, the synthesis of a new type of catalyst, SBA-M (Schiff complex of different metal types grafted on SBA-15) based on a quaternization reaction, is described. Various amounts of ionic liquid were grafted into the pore channels of SBA-15 using the post-grafting method, which allowed the ionic liquid to be grafted into the pore channels restrictively. Notably, over six cycles, SBA-Mn (0.

Heterointerface and Defect Dual Engineering in a Superhydrophilic NiP/WO Microsphere for Boosting Alkaline Hydrogen Evolution Reaction at High Current Density.

Developing a high-performance electrocatalyst for hydrogen evolution reaction (HER) requires a comprehensive consideration of the three key factors, that is, intrinsic activity, electric conductivity, and active site number. Herein, we report the facile synthesis of a self-supported NiP/WO heterointerface microsphere as a highly active and low-cost catalyst for alkaline HER, which has simultaneously addressed these key issues by a joint application of heterointerface construction and defect and architecture engineering strategies. Our density functional theory calculations revealed NiP and WO optimized by the interface coupling effect work in concert to improve the intrinsic activity of the catalyst.

Tuning d-Band Center of Pt by PtCo-PtSn Heterostructure for Enhanced Oxygen Reduction Reaction Performance.

The development of efficient and stable Pt-based catalysts is significant but challenging for fuel cells. Herein, Sn and Co elements are introduced into Pt to form PtCo-PtSn/C heterostructure for enhancing the oxygen reduction reaction (ORR). Electrochemical results indicate that it has remarkable ORR intrinsic activity with a high mass activity (1,158 mA mg Pt) at 0.

Sulfur Vacancy and Ti C T Cocatalyst Synergistically Boosting Interfacial Charge Transfer in 2D/2D Ti C T /ZnIn S Heterostructure for Enhanced Photocatalytic Hydrogen Evolution.

Constructing an efficient photoelectron transfer channel to promote the charge carrier separation is a great challenge for enhancing photocatalytic hydrogen evolution from water. In this work, an ultrathin 2D/2D Ti C T /ZnIn S heterostructure is rationally designed by coupling the ultrathin ZnIn S with few-layered Ti C T via the electrostatic self-assembly strategy. The 2D/2D Ti C T /ZnIn S heterostructure possesses larger contact area and strong electronic interaction to promote the charge carrier transfer at the interface, and the sulfur vacancy on the ZnIn S acting as the electron trap further enhances the separation of the photoinduced electrons and holes.

Design and preparation of three-dimensional hetero-electrocatalysts of NiCo-layered double hydroxide nanosheets incorporated with silver nanoclusters for enhanced oxygen evolution reactions.

Layered double hydroxides (LDHs) are one of the most effective electrocatalysts. However, it is still necessary to improve the lower conductivity and limited active sites of LDHs to enhance their catalytic performance. Targeted generation of vacancies on the catalyst's surface by the incorporation of metal nanoparticles has been explored as a promising strategy to synthesize highly efficient electrocatalysts.

Mn-Modified CuO, CuFeO, and γ-FeO Three-Phase Strong Synergistic Coexistence Catalyst System for NO Reduction by CO with a Wider Active Window.

A series of samples with the precursor's molar ratio of {KMnO}/{CuFeO} = 0, 0.008, 0.010, 0.