Reconfigurable Liquids Stabilized by DNA Surfactants.

Polyelectrolyte microcapsules can be produced either by the layer-by-layer assembly technique or the formation of polyelectrolyte complexes at the liquid-liquid interface. Here, we describe the design and construction of DNA microcapsules using the cooperative assembly of DNA and amine-functionalized polyhedral oligomeric silsesquioxane (POSS-NH) at the oil-water interface. "Janus-like" DNA surfactants (DNASs) assemble in situ at the interface, forming an elastic film.

Self-Assembly of MXene-Surfactants at Liquid-Liquid Interfaces: From Structured Liquids to 3D Aerogels.

2D transition metal carbides and nitrides (MXenes), a class of emerging nanomaterials with intriguing properties, have attracted significant attention in recent years. However, owing to the highly hydrophilic nature of MXene nanosheets, assembly strategies of MXene at liquid-liquid interfaces have been very limited and challenging. Herein, through the cooperative assembly of MXene and amine-functionalized polyhedral oligomeric silsesquioxane at the oil-water interface, we report the formation, assembly, and jamming of a new type MXene-based Janus-like nanoparticle surfactants, termed MXene-surfactants (MXSs), which can significantly enhance the interfacial activity of MXene nanosheets.