Study of catalytic ozonation for tetracycline hydrochloride degradation in water by silicate ore supported CoO.

Tetracycline hydrochloride (TCH) degradation by cobalt modified silicate ore (CoSO) catalytic ozonation in aqueous solution was investigated. CoSO catalyst was synthesized by an impregnation method using Co(NO) as the precursor and natural silicon ore (SO) as the support. The key catalyst preparation conditions (, impregnation concentration, calcination temperature and time) were optimized.

Heterogeneous catalytic ozonation of ciprofloxacin in aqueous solution using a manganese-modified silicate ore.

Manganese modified silicate ore (MnSO) prepared using an impregnation method was used as a heterogeneous ozonation catalyst, and the catalytic activity was evaluated by the degradation of ciprofloxacin (CIP). The results showed that the manganese oxide was successfully loaded onto natural silicate ore (SO). The degradation and mineralization efficiencies of CIP were considerably improved in the presence of MnSO.

A pillared-layered copper(i) halide-based metal-organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift.

We report a new copper halide-based compound [CuIBrCHN] (1) with a 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, compound 1 shows dual emission at 500 nm and 530 nm. As the temperature decreased from 300 K down to 6 K, the luminescent properties of compound 1 show large red shifts of 120 nm and 72 nm, respectively.

Reversible switching of slow magnetic relaxation in a classic lanthanide metal-organic framework system.

The reversible sorption-desorption of terminal coordinated water molecules and the guest molecules can switch slow magnetic relaxation in a classic lanthanide metal-organic framework system, Dy(BTC)(H2O)·DMF and Dy(BTC).

An unusual copper(I) halide-based metal-organic framework with a cationic framework exhibiting the release/adsorption of iodine, ion-exchange and luminescent properties.

A copper(I) halide-based compound with a formula of [Cu4I3(DABCO)2]I3 (DABCO = N,N'-dimethyl-1,4-diazabicyclo[2.2.2]octane) has been prepared by solvothermal reactions.