Thermokinetic behaviour and functional group variation during spontaneous combustion of raw coal and its preoxidised form.

Coal spontaneous combustion (CSC) is a major problem in coal mining. In the vicinity of underground goaf, secondary or repeated oxidation processes of the residual coal inevitably occur, increasing the risk of coal fires. In this study, the thermal reaction behaviour of two types of raw coal samples and three preoxidised coal samples with different oxidation temperatures (80, 130, and 180 °C) were investigated.

Thermal hazards of benzoyl peroxide and its derived process products through theoretical thermodynamics assessment and different calorimetric technologies.

Benzoyl peroxide (BPO) is one of the primary OPs used as an initiator, curing agent, or medicine. Some of the plastic processes use BPO without air for maintaining the efficiency of the entire reaction. However, there have been numerous accidents involving BPO in petrochemical plants, especially those related to fire and explosion, that are due to its unstable thermal properties and peroxy bond (OO).

Effects of UV for Cycloaliphatic Epoxy Resin via Thermokinetic Models, Novel Calorimetric Technology, and Thermogravimetric Analysis.

The cycloaliphatic epoxy resin selected for this study was 3,4-epoxycyclohexane methyl-3'4'-epoxycyclohexyl-carboxylate (EEC). Epoxy resin has numerous applications, such as varnishes, tires, and electronic materials. However, the extensive used of chlorofluorocarbon (CFC) compounds in the last century has resulted in the formation of a hole in the ozone layer.