Biomolecule-Mediated Generation of Ru Nanocatalyst for Sustainable Reduction of Nitrobenzene.

A mild and sustainable synthetic route was followed for the generation of biomolecule-assisted Ru nanocatalyst under open as well as inert atmosphere using the polyphenol morin. The nanocatalyst was characterized thoroughly by powder X-ray diffraction, N adsorption-desorption, high-resolution transmission electron microscopy, dynamic light scattering, X-ray photoelectron spectroscopy, absorption spectroscopy, Fourier transform infrared spectroscopy, fluorescence spectroscopy, thermogravimetric analysis, and inductively coupled plasma optical emission spectrometry. The nanocatalyst reveals excellent catalytic activity for the reduction of several substituted nitrobenzene to aniline derivatives under simple, mild, and environment-friendly conditions.

Spectral anion sensing and γ-radiation induced magnetic modifications of polyphenol generated Ag-nanoparticles.

A fast one step bio-synthesis for in situ preparation of silver nanoparticles is proposed. The method involves reduction of AgNO3 with an aqueous extract of peanut skin, which is a good source of polyphenols. The silver nanoparticles thus synthesized were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), UV-Vis absorption spectroscopy, Fourier Transform infrared (FTIR) spectroscopy and magnetic measurements.