Thickness-Dependence of Exciton-Exciton Annihilation in Halide Perovskite Nanoplatelets.

Exciton-exciton annihilation (EEA) and Auger recombination are detrimental processes occurring in semiconductor optoelectronic devices at high carrier densities. Despite constituting one of the main obstacles for realizing lasing in semiconductor nanocrystals (NCs), the dependencies on NC size are not fully understood, especially for those with both weakly and strongly confined dimensions. Here, we use differential transmission spectroscopy to investigate the dependence of EEA on the physical dimensions of thickness-controlled 2D halide perovskite nanoplatelets (NPls).

Spin Polarization Dynamics of Free Charge Carriers in CsPbI Nanocrystals.

Lead halide perovskites (LHPs) exhibit large spin-orbit coupling (SOC), leading to only twofold-degenerate valence and conduction bands and therefore allowing for efficient optical orientation. This makes them ideal materials to study charge carrier spins. With this study we elucidate the spin dynamics of photoexcited charge carriers and the underlying spin relaxation mechanisms in CsPbI nanocrystals by employing time-resolved differential transmission spectroscopy (DTS).

Fast Electron and Slow Hole Relaxation in InP-Based Colloidal Quantum Dots.

Colloidal InP-based quantum dots are a promising material for light-emitting applications as an environment friendly alternative to their Cd-containing counterparts. Especially for their use in optoelectronic devices, it is essential to understand how charge carriers relax to the emitting state after injection with excess energy and if all of them arrive at this desired state. Herein, we report time-resolved differential transmission measurements on colloidal InP/ZnS and InP/ZnSe core/shell quantum dots.

Oriented Thin Films of Electroactive Triphenylene Catecholate-Based Two-Dimensional Metal-Organic Frameworks.

Two-dimensional triphenylene-based metal-organic frameworks (TP-MOFs) attract significant scientific interest due to their long-range order combined with significant electrical conductivity. The deposition of these structures as oriented films is expected to promote their incorporation into diverse optoelectronic devices. However, to date, a controlled deposition strategy applicable for the different members of this MOF family has not been reported yet.

Boosting Tunable Blue Luminescence of Halide Perovskite Nanoplatelets through Postsynthetic Surface Trap Repair.

The easily tunable emission of halide perovskite nanocrystals throughout the visible spectrum makes them an extremely promising material for light-emitting applications. Whereas high quantum yields and long-term colloidal stability have already been achieved for nanocrystals emitting in the red and green spectral range, the blue region currently lags behind with low quantum yields, broad emission profiles, and insufficient colloidal stability. In this work, we present a facile synthetic approach for obtaining two-dimensional CsPbBr nanoplatelets with monolayer-precise control over their thickness, resulting in sharp photoluminescence and electroluminescence peaks with a tunable emission wavelength between 432 and 497 nm due to quantum confinement.

From Precursor Powders to CsPbX Perovskite Nanowires: One-Pot Synthesis, Growth Mechanism, and Oriented Self-Assembly.

The colloidal synthesis and assembly of semiconductor nanowires continues to attract a great deal of interest. Herein, we describe the single-step ligand-mediated synthesis of single-crystalline CsPbBr perovskite nanowires (NWs) directly from the precursor powders. Studies of the reaction process and the morphological evolution revealed that the initially formed CsPbBr nanocubes are transformed into NWs through an oriented-attachment mechanism.

Dual-comb coherent Raman spectroscopy with lasers of 1-GHz pulse repetition frequency.

We extend the technique of multiplex coherent Raman spectroscopy with two femtosecond mode-locked lasers to oscillators of a pulse repetition frequency of 1 GHz. We demonstrate a spectra of liquids, which span 1100  cm of Raman shifts. At a resolution of 6  cm, their measurement time may be as short as 5 μs for a refresh rate of 2 kHz.

Near-Field Imaging of Phased Array Metasurfaces.

Phased-antenna metasurfaces can impart abrupt, spatially dependent changes to the amplitude, phase, and polarization of light and thus mold wavefronts in a desired fashion. Here we present an experimental and computational near-field study of metasurfaces based on near-resonant V-shaped antennas and connect their near- and far-field optical responses. We show that far fields can be obtained from limited, experimentally obtained knowledge of the near fields, paving the way for experimental near-field characterization of metasurfaces and other optical nanostructures and prediction of their far fields from the near-field measurements.