Crystallization Caught in the Act with Terahertz Spectroscopy: Non-Classical Pathway for l-(+)-Tartaric Acid.

Crystal formation is a highly debated problem. This report shows that the crystallization of l-(+)-tartaric acid from water follows a non-classical path involving intermediate hydrated states. Analytical ultracentrifugation indicates solution clusters of the initial stages aggregate to form an early intermediate.

Terahertz near-field imaging of dielectric resonators.

As an alternative to metallic resonators, dielectric resonators can increase radiation efficiencies of metasurfaces at terahertz frequencies. Such subwavelength resonators made from low-loss dielectric materials operate on the basis of oscillating displacement currents. For full control of electromagnetic waves, it is essential that dielectric resonators operate around their resonant modes.

Double-layered nitrocellulose membrane sample holding technique for THz and FIR spectroscopic measurements.

In terahertz (THz) and far-infrared (FIR) spectroscopic measurements, weak absorption spectral features due to small quantities of test sample can be masked by undesirable etalon fringe artifacts caused by multiple reflections within a pellet or a rigid sample holder. A double-layered nitrocellulose (NC) membrane structure is proposed in this paper as an alternative holder for small quantities of either dry or wet pure (no added polyethylene powder) samples with significantly reduced etalon artifacts. Utilizing a THz time-domain spectroscopy system and a synchrotron source, we demonstrate the performance of the NC structure across the THz/FIR spectrum, benchmarking against pellets holding similarly small quantities of α-lactose powder either with or without different grades of polyethylene powder.

Metamaterial fibres for subdiffraction imaging and focusing at terahertz frequencies over optically long distances.

Using conventional materials, the resolution of focusing and imaging devices is limited by diffraction to about half the wavelength of light, as high spatial frequencies do not propagate in isotropic materials. Wire array metamaterials, because of their extreme anisotropy, can beat this limit; however, focusing with these has only been demonstrated up to microwave frequencies and using propagation over a few wavelengths only. Here we show that the principle can be scaled to frequencies orders of magnitudes higher and to considerably longer propagation lengths.

Low-cost ultra-thin broadband terahertz beam-splitter.

A low-cost terahertz beam-splitter is fabricated using ultra-thin LDPE plastic sheeting coated with a conducting silver layer. The beam splitting ratio is determined as a function of the thickness of the silver layer--thus any required splitting ratio can be printed on demand with a suitable rapid prototyping technology. The low-cost aspect is a consequence of the fact that ultra-thin LDPE sheeting is readily obtainable, known more commonly as domestic plastic wrap or cling wrap.

Low-frequency spectroscopic analysis of monomeric and fibrillar lysozyme.

Terahertz time-domain spectroscopy (THz-TDS) and Fourier transform infrared (FT-IR) spectroscopy were used to generate far-infrared and low-frequency spectral measurements of monomeric lysozyme and lysozyme fibrils. The formation of lysozyme fibrils was verified by the Thioflavin T assay and transmission electron microscopy (TEM). It was evident in the FT-IR spectra that between 150 and 350 cm(-1) the two spectra diverge, with the lysozyme fibrils showing higher absorbance intensity than the monomeric form.

Modelling of sub-wavelength THz sources as Gaussian apertures.

The THz emission point on a nonlinear electro-optical crystal for generating broadband THz radiation is modeled as a radiating Gaussian aperture. With the wavelengths of the infrared pump beam being much smaller than the wavelength components of the generated THz pulse, a THz sub-wavelength radiating aperture with Gaussian profile is effectively created. This paper comprehensively investigates Gaussian apertures in focused THz radiation generation in electro-optical crystals and illustrates the breakdown of the paraxial approximation at low THz frequencies.

Chemical sensing and imaging with pulsed terahertz radiation.

Over the past decade, terahertz spectroscopy has evolved into a versatile tool for chemically selective sensing and imaging applications. In particular, the potential to coherently generate and detect short, and hence, broadband terahertz pulses led to the development of efficient and compact spectrometers for this interesting part of the electromagnetic spectrum, where common packaging materials are transparent and many chemical compounds show characteristic absorptions. Although early proof-of-principle demonstrations have shown the great potential of terahertz spectroscopy for sensing and imaging, the technology still often lacks the required sensitivity and suffers from its intrinsically poor spatial resolution.

Effects of formalin fixing on the terahertz properties of biological tissues.

We demonstrate how the terahertz properties of porcine adipose tissue and skeletal muscle are affected by formalin fixing. Terahertz radiation is sensitive to covalently cross-linked proteins and can be used to probe unique spectroscopic signatures. We study in detail the changes arising from different fixation times and see that formalin fixing reduces the refractive index and the absorption coefficient of the samples in the terahertz regime.

THz porous fibers: design, fabrication and experimental characterization.

Porous fibers have been identified as a means of achieving low losses, low dispersion and high birefringence among THz polymer fibers. By exploiting optical fiber fabrication techniques, two types of THz polymer porous fibers--spider-web and rectangular porous fibers--with 57% and 65% porosity have been fabricated. The effective refractive index measured by terahertz time domain spectroscopy shows a good agreement between the theoretical and experimental results indicating a lower dispersion for THz porous fiber compared to THz microwires.

Sensing the hygroscopicity of polymer and copolymer materials using terahertz time-domain spectroscopy.

We present the hygroscopicity of polymer and copolymer materials in the low terahertz (THz) frequency range using a linear absorption model. We identify COC 6013 and COC 5013 as optimal THz window materials, possessing both low hygroscopicity and high transmission in the THz regime. The correct choice of window material is of significance for transmission THz spectroscopy and of particular interest for THz liquid spectroscopy.

Porous fibers: a novel approach to low loss THz waveguides.

We propose a novel class of optical fiber with a porous transverse cross-section that is created by arranging sub-wavelength air-holes within the core of the fiber. These fibers can offer a combination of low transmission loss and high mode confinement in the THz regime by exploiting the enhancement of the guided mode field that occurs within these sub-wavelength holes. We evaluate the properties of these porous fibers and quantitatively compare their performance relative to that of a solid core air cladded fiber (microwire).

Material thickness optimization for transmission-mode terahertz time-domain spectroscopy.

The thickness of a sample material for a transmission-mode terahertz time-domain spectroscopy (THz-TDS) measurement is the subject of interest in this paper. A sample that is too thick or too thin can raise the problem of measurement uncertainty. Although greater thickness allows the terahertz radiation--or T-rays--to interact more with bulk material, the SNR rolls off with thickness due to signal attenuation.

Dynamic range in terahertz time-domain transmission and reflection spectroscopy.

We present a quantitative method for identification of the dynamic range of the detectable absorption coefficient in the analysis of transmission terahertz (THz) time-domain spectroscopy data. In transmission measurements the largest detectable absorption coefficient is determined by the dynamic range of the THz signals, whereas in reflection measurements the largest detectable absorption coefficient is determined by the scan-to-scan reproducibility of the signal.