Pre-pyrolysis metal and base addition catalyzes pore development and improves organic micropollutant adsorption to pine biochar.

Biochars were produced from pine feedstock pretreated with aqueous base, NaOH, at pH 9 and 11, and alkali and alkaline earth metals (AAEMs) Na, K, Ca, and Mg at 10 and 1 M. The effects of base and AAEM feedstock pretreatment on biochar surface area, pore size distribution, and adsorption capacity of two organic micropollutants (OMPs), 2,4-dichlorophenoxyacetic acid and sulfamethoxazole, from surface water with background dissolved organic matter (DOM) were evaluated. Base pretreatment significantly increased surface area within micropores (<2 nm diameter).