Publications by authors named "Benjamin M Butler"

Article Synopsis
  • Soil plays a key role in the global carbon cycle, and understanding both the quantity and longevity of carbon stored in soils is crucial, especially in less studied regions like sub-Saharan Africa.
  • Previous research has predominantly focused on temperate regions, leaving gaps in knowledge regarding soil carbon dynamics in diverse climates and mineral compositions, which this study aims to address.
  • The findings reveal that organic carbon in moderately weathered soils in seasonal zones persists longer than in highly weathered soils in humid areas, with arid regions showing similar persistence to seasonal zones, suggesting that soil classification based on climatic conditions can enhance predictions of soil behavior under climate change.
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The precipitation of hydrated phases from a chondrite-like Na-Mg-Ca-SO-Cl solution is studied using synchrotron X-ray powder diffraction, under rapid- (360 K h, = 250-80 K, = 3 h) and ultra-slow-freezing (0.3 K day,  = 273-245 K, = 242 days) conditions. The precipitation sequence under slow cooling initially follows the predictions of equilibrium thermodynamics models.

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Soil mineral compositions are often complex and spatially diverse, with each mineral exhibiting characteristic chemical properties that determine the intrinsic total concentration of soil nutrients and their phyto-availability. Defining soil mineral-nutrient relationships is therefore important for understanding the inherent fertility of soils for sustainable nutrient management, and data-driven approaches such as cluster analysis allow for these relations to be assessed in new detail. Here the fuzzy-c-means clustering algorithm was applied to an X-ray powder diffraction (XRPD) dataset of 935 soils from sub-Saharan Africa, with each diffractogram representing a digital signature of a soil's mineralogy.

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X-ray powder diffraction (XRPD) is widely applied for the qualitative and quantitative analysis of soil mineralogy. In recent years, high-throughput XRPD has resulted in soil XRPD datasets containing thousands of samples. The efforts required for conventional approaches of soil XRPD data analysis are currently restrictive for such large data sets, resulting in a need for computational methods that can aid in defining soil property - soil mineralogy relationships.

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Liquid oceans and ice caps, along with ice crusts, have long been considered defining features of the Earth, but space missions and observations have shown that they are in fact common features among many of the solar system's outer planets and their satellites. Interactions with rock-forming materials have produced saline oceans not dissimilar in many respects to those on Earth, where mineral precipitation within frozen seawater plays a significant role in both determining global properties and regulating the environment in which a complex ecosystem of extremophiles exists. Since water is considered an essential ingredient for life, the presence of oceans and ice on other solar system bodies is of great astrobiological interest.

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