Processes leading to reduced and oxidised carbon compounds during corrosion of zero-valent iron in alkaline anoxic conditions.

The Swiss disposal concept foresees that carbon-14 (C) is predominantly released from irradiated steel disposed of in a cement-based repository for low- and intermediate-level radioactive waste. To predict how C migrates in the cementitious environment of the repository near field and subsequently in the host rock, knowledge about the carbon speciation during anoxic steel corrosion in alkaline conditions is therefore essential. To this end, batch-type corrosion experiments with carbon-containing zero-valent iron (ZVI) powders subject to oxidative pre-treatments were carried out in NaOH solution at pH 11 and 12.

Localized, stepwise template growth of functional nanowires from an amino acid-supported framework in a microfluidic chip.

A spatially controlled synthesis of nanowire bundles of the functional crystalline coordination polymer (CP) Ag(I)TCNQ (tetracyanoquinodimethane) from previously fabricated and trapped monovalent silver CP (Ag(I)Cys (cysteine)) using a room-temperature microfluidic-assisted templated growth method is demonstrated. The incorporation of microengineered pneumatic clamps in a two-layer polydimethylsiloxane-based (PDMS) microfluidic platform was used. Apart from guiding the formation of the Ag(I)Cys coordination polymer, this microfluidic approach enables a local trapping of the in situ synthesized structures with a simple pneumatic clamp actuation.

Radiochemistry on chip: towards dose-on-demand synthesis of PET radiopharmaceuticals.

We have developed an integrated microfluidic platform for producing 2-[(18)F]-fluoro-2-deoxy-D-glucose ((18)F-FDG) in continuous flow from a single bolus of radioactive isotope solution, with constant product yields achieved throughout the operation that were comparable to those reported for commercially available vessel-based synthesisers (40-80%). The system would allow researchers to obtain radiopharmaceuticals in a dose-on-demand setting within a few minutes. The flexible architecture of the platform, based on a modular design, can potentially be applied to the synthesis of other radiotracers that require a two-step synthetic approach, and may be adaptable to more complex synthetic routes by implementing additional modules.

A microfluidic device for open loop stripping of volatile organic compounds.

The detection of volatile organic compounds is of great importance for assessing the quality of water. In this contribution, we describe a miniaturized stripping device that allows fast online detection of organic solvents in water. The core component is a glass microfluidic chip that facilitates the creation of an annular-flowing stream of water and nitrogen gas.

Confined synthesis and integration of functional materials in sub-nanoliter volumes.

We present a novel microchip-based approach to combine the synthesis, characterization, and utilization of different functional materials on a single platform. A two-layer microfluidic device comprising 10 parallel actuated reaction chambers with volumes of a few hundred picoliters is used to localize and confine the synthesis, while the surfaces of the reaction chambers comprise an electrode array for direct integration and further characterization of the created crystalline assemblies without the need for further manipulation or positioning devices. First we visualized and evaluated the dynamics of our method by monitoring the formation of a fluorescent metal-organic complex (Zn(bix)).

Development of a novel concept for fate monitoring of biocides in liquid manure and manured soil taking 14C-imazalil as an example.

Biocides are frequently applied in animal houses for veterinary hygiene or pest control. Thus, they may reach liquid manure tanks. Biocides that are not transformed during manure storage enter soil by the application of manure as organic fertilizer.