The limit of periviability is constantly changing as infants born at 22-25 weeks of gestation increasingly survive. The data from our region are limited due to the small numbers of these infants among the NICU population. In this study, we evaluated the survival rates and short-term outcomes among preterm neonates between 22 and 24 weeks of gestation admitted to Tawam Hospital, United Arab Emirates.
View Article and Find Full Text PDFWe report on the first, to our knowledge, room-temperature continuous-wave laser operation of Tm,Ho-codoped barium and strontium fluoride crystals at ∼2.1 µm. The 3 at.
View Article and Find Full Text PDFSiO electrodes are promising for high-energy-density lithium-ion batteries (LIBs) due to their ability to mitigate volume expansion-induced degradation. Here, we investigate the surface dynamics of SiO thin-film electrodes cycled in different carbonate-based electrolytes using a combination of ex situ X-ray photoelectron spectroscopy (XPS) and operando synchrotron X-ray reflectivity analyses. The thin-film geometry allows us to probe the depth-dependent chemical composition and electron density from surface to current collector through the solid electrolyte interphase (SEI), the active material, and the thickness evolution during cycling.
View Article and Find Full Text PDFNew battery technologies are currently under development, and among them, all-solid-state batteries should deliver better electrochemical performance and enhanced safety. Composite solid electrolytes, combining a solid polymer electrolyte (SPE) and a ceramic electrolyte (CE), should then provide high ionic conductivity coupled to high mechanical stability. To date, this synergy has not yet been reached due to the complexity of the Li-ion transport within the hybrid solid electrolyte, especially at the SPE/CE interface currently considered the limiting step.
View Article and Find Full Text PDFBackground: Morocco is currently undergoing rapid changes in diets and lifestyles, influenced by globalization and urbanization, leading to a shift away from the Mediterranean diet (MedDiet) toward Western diets.
Objective: Describe and explore the food consumption patterns of the population of Kenitra province and their adherence to the MedDiet using a validated survey.
Method: The current cross-sectional study involved 442 respondents from Kenitra province, comprising individuals aged 18 and above.
Depressed-cladding surface channel waveguides were inscribed in a 0.5 at.% Pr:LiYF crystal by femtosecond Direct Laser Writing.
View Article and Find Full Text PDFRoom temperature ionic liquids (ILs) can create a strong accumulation of charges at solid interfaces by forming a very thin and dense electrical double layer (EDL). The structure of this EDL has important consequences in numerous applications involving ILs, for example, in supercapacitors, sensors, and lubricants, by impacting the interfacial capacitance, the charge carrier density of semiconductors, as well as the frictional properties of the interfaces. We have studied the interfacial structure of a long chain imidazolium-based IL (1-octyl-3-methylimidazolium dicyanamide) on several substrates: mica, silica, silicon, and molybdenum disulfide (MoS), using atomic force microscopy (AFM) experiments and molecular dynamics (MD) simulations.
View Article and Find Full Text PDFWe report on the first, to the best of our knowledge, continuous-wave laser operation of a Tm,Ho-codoped calcium fluoride crystal at ∼2.1 µm. Tm,Ho:CaF crystals were grown by the Bridgman method, and their spectroscopic properties were studied.
View Article and Find Full Text PDFWe report on sub-50 fs pulse generation from a passively mode-locked Yb:SrF laser pumped with a spatially single-mode, fiber-coupled laser diode at 976 nm. In the continuous-wave regime, the Yb:SrF laser generated a maximum output power of 704 mW at 1048 nm with a threshold of 64 mW and a slope efficiency of 77.2%.
View Article and Find Full Text PDFMetal-organic frameworks are a class of porous materials that show promising properties in the field of microelectronics. To reach industrial use of these materials, gas phase techniques are often preferred and were recently introduced. However, the thicknesses achieved are not sufficient, limiting further development.
View Article and Find Full Text PDFUsing Si as anode materials for Li-ion batteries remain challenging due to its morphological evolution and SEI modification upon cycling. The present work aims at developing a composite consisting of carbon-coated Si nanoparticles (Si@C NPs) intimately embedded in a three-dimensional (3D) graphene hydrogel (GHG) architecture to stabilize Si inside LiB electrodes. Instead of simply mixing both components, the novelty of the synthesis procedure lies in the in situ hydrothermal process, which was shown to successfully yield graphene oxide reduction, 3D graphene assembly production, and homogeneous distribution of Si@C NPs in the GHG matrix.
View Article and Find Full Text PDFWe report on the first, to our knowledge, mid-infrared laser operation of two Er-doped barium-containing fluorite-type crystals, BaF and (Sr,Ba)F, featuring a low-phonon energy behavior. A continuous wave 4.9 at.
View Article and Find Full Text PDFIn order to contribute to the reduction of nutritional deficiencies in Morocco, this study was undertaken to develop a healthier tortilla with higher iron and protein, while maintaining adequate technological and sensory qualities. Composite durum wheat flour enriched with 20, 25, 30, and 35% chickpea flour was assessed for nutritional, functional, and technological properties. Then, we selected two composite blends of 75:25 and 70:30 of durum wheat and chickpea flours for making tortillas to study nutritional, technological, and sensorial qualities.
View Article and Find Full Text PDFWhile the development and manufacture of pandemic vaccines is a daunting task, the greatest challenge lies in how to deliver these vaccines to billions of people around the world. This requires an efficient strategy of deliveries, at constrained costs and deadlines. This paper proposes an exact analytical approach and operational strategy to the logistics of any pandemic vaccination efforts, applicable both to sparsely populated areas or deficient infrastructure, and to very dense urban fabrics where mobility is highly constrained.
View Article and Find Full Text PDFWe report on a continuous-wave (CW) and passively mode-locked operation of a fluorite-type Yb:BaF crystal. Pumped with a spatially single-mode, fiber-coupled InGaAs laser diode at 976 nm, the Yb:BaF laser generated a maximum CW output power of 512 mW at 1054.4 nm, corresponding to a laser threshold of 36.
View Article and Find Full Text PDFMid-infrared Er:CaF laser operating on the I → I transition is developed. Its power scaling capabilities and thermo-optics (fractional heat loading and thermal lensing) are compared under pumping into the I and I states. Using a 4.
View Article and Find Full Text PDFWe present a free-running 80-MHz dual-comb polarization-multiplexed solid-state laser which delivers 1.8 W of average power with 110-fs pulse duration per comb. With a high-sensitivity pump-probe setup, we apply this free-running dual-comb laser to picosecond ultrasonic measurements.
View Article and Find Full Text PDFWe report on the mid-infrared laser operation of a cubic 15 at.% : crystal. In the quasi-continuous-wave regime, the peak power reaches 255 mW at 2.
View Article and Find Full Text PDFThe coupling protocols combining photoemission spectroscopy and other characterization methods such as electrochemical, electrical, optical, thermal, or magnetic paved the way to considerable progress in the field of materials science. Access to complementary data on the same object is relevant, but in the vast majority of cases, it is carried out sequentially and separately. This raises the complex question of the equivalence of the analyzed surfaces subjected to these different characterizations.
View Article and Find Full Text PDFFaba beans are acknowledged as a good source of proteins, minerals, fibers, vitamins and antioxidants. A blending study was undertaken in order to prepare naturally bread from enriched flours with added nutritional value, mainly in terms of Iron and proteins. Enriched flours were prepared with varied levels (25, 30, 35 and 40%) of whole faba bean flour to assess the effects of this substitution on their nutritional and technological properties.
View Article and Find Full Text PDFWe report on a novel approach to fabricate channel (ridge) waveguides (WGs) in bulk crystals using precision diamond saw dicing. The channels feature a high depth-to-width aspect ratio (deep dicing). The proof-of-the-concept is shown for a Tm:LiYF fluoride crystal.
View Article and Find Full Text PDFWe reported a new perspective on the correlation between the electronic structure of an ionic liquid (IL)-based electrolyte probed by X-ray photoelectron spectroscopy and the transport properties analyzed by impedance spectroscopy. We highlighted the core level chemical shifts of 1-hexyl-3-methylimidazolium (bis(trifluoromethanesulfonyl)imide) (CCImTFSI), 1-hexyl-3-methylimidazolium bis(fluorosulfonyl)imide (CCImFSI), and 1-hexyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide (CCCImTFSI) laden with LiTFSI salt and vinylene carbonate (VC) or fluoroethylene carbonate (FEC) with regard to the transport properties of cations and anions. We pointed out based on detailed binding energy shift analyses a clear effect of the anion on the local organization of Li ions.
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