Storage Optimization of Transmission Holographic Gratings in Photohydrogels.

The development and optimization of holographic materials represent a great challenge today. These materials must be synthesized according to the characteristics that are desirable in photonic devices whose application is the object of investigation. In certain holographic sensors and biosensors, it is essential that the recording material be stable in liquid media.

Liquid crystal doped photopolymer micro-droplets printed by a simple and clean laser-induced forward transfer process.

We print a tunable photopolymer (photopolymer dispersed liquid crystal -PDLC), using the laser-induced direct transfer technique without absorber layer, which was a challenge for this technique given the low absorption and high viscosity of PDLC, and which had not been achieved so far to our knowledge. This makes the LIFT printing process faster and cleaner and achieves a high-quality printed droplet (aspheric profile and low roughness). A femtosecond laser was needed to reach sufficiently peak energies to induce nonlinear absorption and eject the polymer onto a substrate.

Holographic Lens Resolution Using the Convolution Theorem.

The similarity between object and image of negative asymmetrical holographic lenses (HLs) stored in a low-toxicity photopolymer has been evaluated theoretically and experimentally. Asymmetrical experimental setups with negative focal lengths have been used to obtain HLs. For this purpose, the resolution of the HLs was calculated using the convolution theorem.

Green and wide acceptance angle solar concentrators.

A low-toxicity photopolymer was employed to prepare holographic solar concentrators (HSCs). The main aim of this study is to obtain a versatile holographic element to concentrate the sunlight from different relative positions of the Sun during the day, avoiding the need of expensive tracking systems. Multiplexed holographic elements that combine symmetric and asymmetric holographic lenses of low frequency (545 l/mm) have been recorded in the same plate to concentrate the sunlight from sunrise to sunset.

Processing of Holographic Hydrogels in Liquid Media: A Study by High-Performance Liquid Chromatography and Diffraction Efficiency.

The storage of time-stable holographic gratings in hydrogel matrices when the material is immersed in aqueous media is a real challenge at present. The optimization of the storage stages of the holograms must be properly investigated to identify the most suitable development processes. For this reason, this work is focused on the study of the optimization of the washing stages of the hydrogels based on acrylamide and ,'-methylenebis(acrylamide) once unslanted transmission holograms have been stored.

Adulterant Detection in Peppermint Oil by Means of Holographic Photopolymers Based on Composite Materials with Liquid Crystal.

Diffraction gratings are recorded in a holographic photopolymer containing nematic liquid crystal and peppermint oil. The presence of the oil modifies the polymerization and the holographic response. The composite containing oil adulterated with triethyl citrate obtains a diffraction efficiency related to the oil's purity.

Qualitative disorder measurements from backscattering spectra through an optical fiber.

In the processes related to the development of cancer, there are different genetic and epigenetic events involved that result in structural changes of the affected cells. In the early stages of the disease, these changes occur at the nanoscale, remaining undetectable by conventional light microscopy, due to diffraction-limited resolution (∼250 - 550 nm). In this sense, a technique termed partial wave spectroscopy (PWS) allows the detection of these nanostructural changes by measuring a statistical parameter called disorder strength ( ).

Unitary matrix approach for a precise voltage dependent characterization of reflective liquid crystal devices by average Stokes polarimetry.

Precise characterization of parallel-aligned liquid crystal on silicon microdisplays has an important impact in many advanced photonics applications. We show liquid crystal on silicon (LCoS) modeled as a non-absorbent reciprocal device. Combined with time-average Stokes polarimetry, LCoS enables us to demonstrate robust measurements across the whole applied voltage range for the retardance and its flicker, and also as a novelty for the director orientation.

Accurate, Efficient and Rigorous Numerical Analysis of 3D H-PDLC Gratings.

This work presents recent results derived from the rigorous modelling of holographic polymer-dispersed liquid crystal (H-PDLC) gratings. More precisely, the diffractive properties of transmission gratings are the focus of this research. This work extends previous analysis performed by the authors but includes new features and approaches.

Phase-Shift Optimization in AA/PVA Photopolymers by High-Frequency Pulsed Laser.

Photopolymers can be used to fabricate different holographic optical elements, although maximization of the phase-shift in photopolymers has been a challenge for the last few decades. Different material compositions and irradiation conditions have been studied in order to achieve it. One of the main conclusions has been that with continuous laser exposure better results are achieved.

Analysis of the Imaging Characteristics of Holographic Waveguides Recorded in Photopolymers.

In this work, we study the imaging characteristics of an optical see-through display based on a holographic waveguide. To fabricate this device, two transmission holograms are recorded on a photopolymer material attached to a glass substrate. The role of the holograms is to couple the incident light between air and the glass substrate, accomplishing total internal reflection.

Aberration-Based Quality Metrics in Holographic Lenses.

Aberrations and the image quality of holographic lenses were evaluated by a Hartmann-Shack (HS) wavefront sensor. Two lenses, one recorded with a symmetrical configuration and the other with an asymmetrical one, were stored in a photopolymer called Biophotopol. Each was reconstructed with two different wavelengths, 473 nm and 633 nm.

Complex Diffractive Optical Elements Stored in Photopolymers.

We study the recording of complex diffractive elements, such as achromatic lenses, fork gratings or axicons. Using a 3-D diffusion model, previously validated, we are able to predict the behavior of photopolymer during recording. The experimental recording of these complex elements is possible thanks to a new generation spatial light modulator capable of generating periodic and aperiodic profiles.

Diffractive and Interferometric Characterization of Nanostructured Photopolymer for Sharp Diffractive Optical Elements Recording.

We study the behavior of a nanoparticle-polymer composite (NPC) material, based on a thiol-ene monomer system, working with long grating spacing. Thus, we evaluate the suitability of the NPC for storing complex diffractive optical elements with sharp profiles, such as blazed gratings. Using holographic methods, we measure the "apparent" diffusion of the material and the influence of the spatial period on this diffusion.

Numerical Analysis of H-PDLC Using the Split-Field Finite-Difference Time-Domain Method.

In this work, an accurate numerical modeling of the diffraction properties of transmission holographic polymer dispersed liquid crystal (H-PDLC) gratings is presented. The method considers ellipsoid geometry-based liquid crystal (LC) droplets with random properties regarding size and location across the H-PLDC layer and also the non-homogeneous orientation of the LC director within the droplet. The direction of the LC director inside the droplets can be varied to reproduce the effects of the external voltage applied in H-PDLC-based gratings.

Holographic Lenses in an Environment-Friendly Photopolymer.

In this paper, we theoretically and experimentally evaluated the quality of volume phase transmission lenses stored in an environmentally friendly photopolymer. Holographic lenses (HLs) were obtained using symmetrical and asymmetrical experimental setups with the same positive and negative focal length and pupil diameter. The image quality was evaluated from the calculation of the modulation transfer function (MTF) by capturing the point spread function (PSF) with a charge-coupled device (CCD).

Holographic Characteristics of Photopolymers Containing Different Mixtures of Nematic Liquid Crystals.

A holographic polymer dispersed liquid crystal (HPDLC) is used to record holographic diffraction gratings. Several mixtures of nematic liquid crystals (LC) are used as components of the HPDLC to evaluate their influence in static and dynamic basic properties. The diffraction efficiency obtained in the reconstruction of the holograms is evaluated to compare the influence of the different LC.

Influence of Tert-Butylthiol and Tetrahydrofuran on the Holographic Characteristics of a Polymer Dispersed Liquid Crystal: A Research Line Toward a Specific Sensor for Natural Gas and Liquefied Petroleum Gas.

Tert-Butylthiol (TBT) and tetrahydrothiophene (THT) are odorant substances added to natural gas and liquefied petroleum gas to help their detection by the human smell. In this research, TBT and THT are incorporated into a holographic polymer-dispersed liquid crystal and their influence in the main holographic characteristics of the photopolymer are studied in order to open the way towards the design of a holographic sensor to detect natural gas and liquefied petroleum gas.

Combining average molecular tilt and flicker for management of depolarized light in parallel-aligned liquid crystal devices for broadband and wide-angle illumination.

We demonstrate a complete semiphysical and analytical model describing the angular and wavelength dependencies not only of retardance, but also its flicker, in parallel aligned liquid crystal (PA-LC) devices. It relies on the fitting of the molecules' equivalent tilt angle as a function of applied voltage. The wide range of calculations it offers without requiring extensive characterization makes the model unique.

Holographic waveguides in photopolymers.

The possibilities that offer the holographic optical elements for photovoltaic and "see through display" applications open new windows for holographic recording materials. In this sense, some specific characteristics are required for each particular application. Waveguides are one of the key elements for these applications.

Simplified physical modeling of parallel-aligned liquid crystal devices at highly non-linear tilt angle profiles.

In recent works, we demonstrated the accuracy and physical relevance of a highly simplified reverse-engineering analytical model for a parallel-aligned liquid crystal on silicon devices (PA-LCoS). Both experimental measurements and computational simulations applying the rigorous split-field finite difference time domain (SF-FDTD) technique led to this conclusion in the low applied voltages range. In this paper, we develop a complete rigorous validation covering the full range of possible applied voltages, including highly non-linear liquid crystal (LC) tilt angle profiles.

Additives Type Schiff's Base as Modifiers of the Optical Response in Holographic Polymer-Dispersed Liquid Crystals.

Schiff's bases with specific π-electron system have been synthesized and used as additives in holographic polymer-dispersed liquid crystals. It was observed that these substances modify different parameters such as current intensity, voltage, and diffracted light intensity. In addition, the maximum diffraction efficiency obtained in the reconstruction of the holograms is related to the additive molecule.

Modeling Diffractive Lenses Recording in Environmentally Friendly Photopolymer.

The improvements made in diffusion models simulating phase image recording in photopolymers enable the optimization of a wide range of complex diffractive optical elements (DOEs), while the miniaturization of spatial light modulators makes it possible to generate both symmetric and non-symmetric DOEs. In addition, there is increasing interest in the design of new friendly recording materials. In this respect, photopolymers are a promising material due to their optical properties.

Blazed Gratings Recorded in Absorbent Photopolymers.

Phase diffractive optical elements, which have many interesting applications, are usually fabricated using a photoresist. In this paper, they were made using a hybrid optic-digital system and a photopolymer as recording medium. We analyzed the characteristics of the input and recording light and then simulated the generation of blazed gratings with different spatial periods in different types of photopolymers using a diffusion model.