Long-range transport and directed assembly of charged colloids under aperiodic electrodiffusiophoresis.

Faradaic reactions often lead to undesirable side effects during the application of electric fields. Therefore, experimental designs often avoid faradaic reactions by working at low voltages or at high frequencies, where the electrodes behave as ideally polarizable. In this work, we show how faradaic processes under ac fields can be used advantageously to effect long-range transport, focusing and assembly of charged colloids.

Visualization of Concentration Gradients and Colloidal Dynamics under Electrodiffusiophoresis.

In this work, we present an experimental study of the dynamics of charged colloids under direct currents and gradients of chemical species (electrodiffusiophoresis). In our approach, we simultaneously visualize the development of concentration polarization and the ensuing dynamics of charged colloids near electrodes. With the aid of confocal microscopy and fluorescent probes, we show that the passage of current through water confined between electrodes, separated about a hundred microns, results in significant pH gradients.

Electric polarizability of metallodielectric Janus particles in electrolyte solutions.

Metallodielectric Janus particles (JPs) and electric fields have been a useful combination for the development of innovative concepts on AC electrokinetics, directed transport and collective dynamics. The polarizability, and its frequency dependence, underlie the rich behavior exhibited by JPs. Nonetheless, direct measurements of polarizability are few and the interplay of different mechanisms remains unclear.

Shape-based separation of micro-/nanoparticles in liquid phases.

The production of particles with shape-specific properties is reliant upon the separation of micro-/nanoparticles of particular shapes from particle mixtures of similar volumes. However, compared to a large number of size-based particle separation methods, shape-based separation methods have not been adequately explored. We review various up-to-date approaches to shape-based separation of rigid micro-/nanoparticles in liquid phases including size exclusion chromatography, field flow fractionation, deterministic lateral displacement, inertial focusing, electrophoresis, magnetophoresis, self-assembly precipitation, and centrifugation.