Globally, contamination of agricultural soils by phthalate esters (PAEs) caused by direct consumption of plastic mulch films has been confirmed. The most widely used plasticizer is di (2-ethylhexyl) phthalate (DEHP), which is a more recalcitrant endocrine-disrupting chemical (EDC). Because of its low solubility and hydrophobicity, it remains in the soil longer, causes bioaccumulation in agricultural products, and has negative repercussions for food safety.
View Article and Find Full Text PDFBiochim Biophys Acta Proteins Proteom
January 2024
Implementing hyperthermostable carbonic anhydrases into CO capture and storage technologies in order to increase the rate of CO absorption from the industrial flue gases is of great importance from technical and economical points of view. The present study employed a combination of in silico tools to further improve thermostability of a known thermostable carbonic anhydrase from Sulfurihydrogenibium yellowstonense. Experimental results showed that our rationally engineered K100G mutant not only retained the overall structure and catalytic efficiency but also showed a 3 °C increase in the melting temperature and a two-fold improvement in the enzyme half-life at 85 °C.
View Article and Find Full Text PDFMany companies in the food industry apply reverse osmosis (RO) membranes to ensure high-quality reuse of water. Biofouling is however, a common, recalcitrant and recurring problem that blocks transport over membranes and decreases the water recovery. Microorganisms adhering to membranes may form biofilm and produce an extracellular matrix, which protects against external stress and ensures continuous attachment.
View Article and Find Full Text PDFBio surfactants are natural surfactants that induce emulsification, displacement, increased solubility, and mobility of hydrophobic organic compounds. In this study, the gene expression of biosurfactant production genes by in the presence of sodium dodecyl sulfate coated iron nanostructure (Fe/SDS) were evaluated. Emulsification Index and Surface Tension reduction test to check stability and emulsification the rhamnolipid were done.
View Article and Find Full Text PDFHydrogen sulfide (HS) is a super toxic substance that produces SO gases when combusted. Therefore, it should be removed from gas streams. Biodesulfurization is one of the developing methods for removing sulfide.
View Article and Find Full Text PDFSteel is one of the mainly used materials in the oil and gas industry. However, it is susceptible to the marine corrosion, which 20% of the total marine corrosion is caused by microbiologically influenced corrosion (MIC). The economic and environmental impacts of corrosion are significant, and it is crucial to fight against corrosion in a proper sustainability context and environmental-friendly methods.
View Article and Find Full Text PDFBiosurfactants are amphiphilic molecules composed of a hydrophilic and hydrophobic moiety and had the ability to penetrate into different phases to reduce the surface tension. This features caused to oil recovery, lubrication and facilities of crude oil in pipeline. In current research Biosurfactant-producing strain was isolated from the storage tanks of the Isfahan Oil Refining Company in Iran, and screened by oil expansion test, droplet collapse, and surface tension reduction measurement.
View Article and Find Full Text PDFIn this research, a zinc oxide/copper oxide/graphene oxide (ZnO/CuO/GO) nanophotocatalyst was synthesized for photodegradation of aniline as a pollutant, upon exposure to ultraviolet light (UV). Three variables including initial aniline concentration, the nanophotocatalyst dosage, and pH were designed. The statistical test and optimal conditions were determined.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
November 2020
Recently, nanomaterials have been introduced as a new generation of inhibitors to control the microbiologically influenced corrosion (MIC). In this study, copper nanoparticles doped carbon quantum dots (Cu/CQDs) nanohybrid was used as an inhibitor to reduce the MIC. FESEM, EDS, FTIR, and XRD were used to characterize the nanohybrid.
View Article and Find Full Text PDFTransition metal sulfide semiconductors have achieved significant attention in the field of photocatalysis and degradation of pollutants. MoS with a two dimensional (2D) layered structure, a narrow bandgap and the ability of getting excited while being exposed to visible light, has demonstrated great potential in visible-light-driven photocatalysts. However, it possesses fast-paced recombination of charges.
View Article and Find Full Text PDFNowadays, fossil fuel is the most important source of energy. However, the sulfur oxide release through oxidation of the available sulfur and the resultant air pollution has turned into an issue. In biodesulfurization (BDS) process, the sulfur from the recalcitrant organic compounds dissolved in crude oil fractions will be removed biologically.
View Article and Find Full Text PDFThe application of dibenzothiophene (DBT) as a source of energy leads to air pollution. The key solution to overcome this drawback is desulfurization. Magnetic nanoparticles have shown an excellent performance in the desulfurization of dibenzothiophene.
View Article and Find Full Text PDFExploiting synergism between plants and microbes offers a potential means of remediating soils contaminated with petroleum hydrocarbons (PHCs). Salinity alters the physicochemical characteristics of soils and suppresses the growth of both plants and soil microbes, so the bioremediation of saline soils requires the use of plants and in microbes which can tolerate salinity. This review focuses on the management of PHC-contaminated saline soils, surveying what is currently known with respect to the potential of halophytes (plants adapted to saline environments) acting in concert with synergistic microbes to degrade PHCs.
View Article and Find Full Text PDFThe separation process is the main stage of recombinant production. With the advancement of nanotechnology and the development of magnetic nanoparticles, these structures are increasingly used in different applications. In the present study, we produced the recombinant human growth hormone from Pichia pastoris and for protein separation provided the surfaces similar to chromatographic columns on the surface of magnetic nanoparticles.
View Article and Find Full Text PDFHealth is an important element that influences the level of development in a community. Studies show that tooth decay has been prevalent recently. Starch incorporating curcumin can serve as an alternative approach in preventing the activity of Streptococcus mutans attributed to biofilm and plaque formation on teeth.
View Article and Find Full Text PDFBiodesulfurization (BDS) is an environmentally friendly desulfurizing process with the potential of replacing or adding to the current expensive technologies for sulfur removal from fossil fuels. The BDS, however, still suffers from low biocatalyst activity. One reason is repression of promoter transcription in presence of inorganic sulfate that impedes translation of Dsz enzymes required for desulfurization pathway.
View Article and Find Full Text PDFThe aim of this study was to evaluate the effects of iron (Fe)/SDS and gold (Au) nanoparticles on growth and biosurfactant production of . The concentrations of the nanoparticles used were 1, 500 and 1000 mg/l. In this research, the surface tension of biosurfactant, dry weight of biosurfactant and biomass, emulsification indexes (E) were measured and transmission electron microscopy analysis was used to monitor the nanoparticles.
View Article and Find Full Text PDFIn this research, we attempt to study biosurfactant production by Pseudomonas aeruginosa using Fe/starch nanoparticles. Fe/starch showed no bacterial toxicity at 1 mg/ml and increased the growth rate and biosurfactant production up to 23.91 and 20.
View Article and Find Full Text PDFRecently, bacterial cellulose (BC) based wound dressing have raised significant interests in medical fields. However, to our best knowledge, it is apparent that the BC itself has no antibacterial activity. In this study, we optimized graphene oxide-silver (GO-Ag) nanohybrid synthesis using Response Surface Methodology and impregnate it to BC and carefully investigate their antibacterial activities against both the Gram-negative bacteria and the Gram-positive bacteria .
View Article and Find Full Text PDFThis study was conducted to investigate biodenitrification efficiency with starch-stabilized nano zero valent iron (S-nZVI) as the additional electron donor in the presence of SO in aqueous solutions, under anaerobic conditions. The main challenge for nZVI application is their tendency to agglomeration, thereby resulting in loss of reactivity that necessitates the use of stabilizers to improve their stability. In this study, S-nZVI was synthesized by chemical reduction method with starch as a stabilizer.
View Article and Find Full Text PDFToday, crude oil is an important source of energy and environmental contamination due to the continued use of petroleum products is a matter or urgent concern. In this work, two technological platforms, namely, the use of a robust desulfurizing bacteria and the use of nanotechnology to decorate the surface of the bacteria with nanoparticles (NP), were combined to enhance biodesulfurization (BDS). BDS is an ecologically friendly method for desulfurizing petroleum products while avoiding damage to the hydrocarbons due to the high temperatures normally associated with physical desulfurization methods.
View Article and Find Full Text PDFThe application of Fe3 O4 nanoparticles to the separation of desulfurizing bacterial cells and their influence on the desulfurization activity and reusability of the two bacterial strains Rhodococcus erythropolis FMF and R. erythropolis IGTS8 were investigated. Magnetite nanoparticles were synthesized via the reverse coprecipitation method.
View Article and Find Full Text PDFA novel desulfurizing bacterium has been isolated from oil-contaminated soils in Khuzestan. The ability for dibenzothiophene desulfurization and its biochemical pathway were investigated. The bacterium was identified as Gordonia sp.
View Article and Find Full Text PDFFor the first time, growing cells of Gordonia alkanivorans RIPI90A were used for biodesulfurization (BDS) of diesel. This process was carried out in an internal airlift bioreactor. BDS parameters (oil/water phase ratio and initial sulfur concentration) were optimized in flasks using response surface methodology.
View Article and Find Full Text PDFAs a significant discovery in the 20th century, carbon nanotubes are attracting particular attention in many unique fields such as electronics, catalysts, hydrogen storage composites, gas sensors, drug delivery, medical diagnostics, therapeutics and nanofluids. In this project, we focus on self-assembled synthetic special natural protein alpha-lactalbumin nanotubes with different (straight, waved, coiled, regularly bent, branched, beaded) shapes, nanospherical particles, nanorods, nanowires, nanopores, polyhedral (hexagonal network, spherical, cubic) nanostructures, nanochannels, nanofibers, nanosheets, nanoleaves, nanowave branched structures, nanobeads, nanoflowers, nanocapsules, novel nano-hybrids consisting of tubes and rods (new core-shell), nanocrystal shapes, apiary or cobweb, branched nanotubes with Y-junctions, nano membrane structures, nano sweep symmetrical shape, nano sponge structures, nano helical homogeneous structures and nano perpendicular and horizontal stable hollow single-walled natural protein nanotubes (NPNTs). These were successfully synthesized by the chemical hydrolysis sol--gel method and partial biochemical enzymatic hydrolysis by cleavage sites (Asp-X and Glu-X) of the milk protein a-lactalbumin by using various organic surfactants, pH controller functions and divalent metallic salt ions as a binding site or ions ligand formation between two bio-based building blocks to form remarkable various new morphologies in appearance of nanoemulsions and clear green nanofluids, for application in the diet nutrition food science and pharmaceutical industry.
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