Flow-through optosensing of 1-naphthaleneacetic acid in water and apples by heavy atom induced-room temperature phosphorescence measurements.

A sensitive and selective phosphorimetric method for the determination of 1-naphthaleneacetic acid (1-NAA) based on a flow-injection system connected to a flow cell packed with a solid support and placed in the sample compartment of a conventional luminescence spectrometer is described. A non-ionic solid polymeric resin Amberlite XAD-7 is used for the packing. After injection of the sample, 1-NAA is on-line retained in the packed resin and measurements of the heavy atom induced (HAI)-room temperature phosphorescence (RTP) emission (lambda(ex)/lambda(em)=292/490nm) from this native luminescent compound are taken.

Flow injection determination of nitrite by fluorescence quenching.

A simple, sensitive and selective fluorimetric method for the determination of nitrite ion in waters using a merging zones flow injection system is described. The fluorimetric determination is based on the measurement of the quenching effect produced by nitrite on proflavine (3,6-diaminoacridine) fluorescence (lambda(ex)/lambda(em)=290/519nm). The optimum experimental conditions were investigated by merging 0.