Green Extraction Techniques as Advanced Sample Preparation Approaches in Biological, Food, and Environmental Matrices: A Review.

Green extraction techniques (GreETs) emerged in the last decade as greener and sustainable alternatives to classical sample preparation procedures aiming to improve the selectivity and sensitivity of analytical methods, simultaneously reducing the deleterious side effects of classical extraction techniques (CETs) for both the operator and the environment. The implementation of improved processes that overcome the main constraints of classical methods in terms of efficiency and ability to minimize or eliminate the use and generation of harmful substances will promote more efficient use of energy and resources in close association with the principles supporting the concept of green chemistry. The current review aims to update the state of the art of some cutting-edge GreETs developed and implemented in recent years focusing on the improvement of the main analytical features, practical aspects, and relevant applications in the biological, food, and environmental fields.

Development of highly hydrophobic fabric phase sorptive extraction membranes and exploring their applications for the rapid determination of tocopherols in edible oils analyzed by high pressure liquid chromatography-diode array detection.

Α novel, green, and facile fabric phase sorptive extraction (FPSE) prior to high pressure liquid chromatography with diode array detection (HPLC-DAD) methodology was developed for the efficient extraction and quantitative determination of tocopherols (α-, sum of (β+γ), and δ-) in edible oils. Among several highly hydrophobic FPSE membranes, sol-gel polycaprolactone-polydimethylsiloxane-polycaprolactone (sol-gel PCAP-PDMS-PCAP) coated polyester FPSE membrane was found as the most efficient in extracting tocopherol homologues from edible oil samples. To maximize the extraction efficiency of FPSE membrane, major parameters of FPSE including the membrane size, sample loading time, the choice of the appropriate elution solvent and the elution solvent volume, desorption time, and the influence of stirring were systematically optimized.