Effect of electrostatic interactions on rejection of capsular and spherical particles from porous membranes: theory and experiment.

Hypotheses: Particle rejection from porous membranes will increase when particle and membrane carry like charges. The influence of charge on particle rejection can be modeled by first solving the Poisson-Boltzmann equation for the electrostatic particle-pore wall interaction energy, enabling one to predict the cross sectional particle concentration in a pore. Rejection coefficients can then be predicted by combining the Boltzmann factor with a hydrodynamic lag coefficient.