Natural extracts of plant origin are used as anti-aging compounds of biodegradable polymers. Coffee, cocoa, or cinnamon extracts in amounts from 0.5 to 10 wt.
View Article and Find Full Text PDFThe article presents research on the potential use of organometallic compounds with the addition of antimony (III) oxide SbO as a coating additive that will make coatings susceptible to electroless metallization after prior surface irradiation with 193 nm wavelength laser radiation and a different number of laser pulses. The surface modification and activation effects were assessed by optical-imagining as well as by scanning electron microscopy (SEM) with energy dispersive analysis (EDX). It was found that the presence of SbO in the coating made it possible to reduce the content of the copper complex, causing an intensive surface ablation, resulting in the formation of a conical structure with a higher content of metallic copper nuclei.
View Article and Find Full Text PDFPolyurethane coatings containing copper(II) L-tyrosine and glass microspheres were laser irradiated and underwent electroless metallization. Various sizes of glass microspheres were incorporated into the polyurethane coating matrix in order to examine their effects on surface activation and electroless metallization. The surface of the coatings was activated by using ArF excimer laser emitting ultraviolet radiation (λ = 193 nm) using different number of laser pulses and their fluence.
View Article and Find Full Text PDFThis paper presents a comparative assessment of Cu(acac) and {[Cu(μ-'-NO) (L-arg)(2,2'-bpy)]·NO} as potential precursors for the electroless metallization of laser activated polymer materials. Coatings consisting of polyurethane resin, one of the two mentioned precursor compounds, and antimony oxide (SbO), as a compound strongly absorbing infrared radiation, were applied on the polycarbonate substrate. The coatings were activated with infrared Nd: YAG laser radiation (λ = 1064 nm) and electroless metallized.
View Article and Find Full Text PDFSelective metallization of polymeric materials using the technique known as laser direct structuring (LDS) is intensively developed. In this technique, metallized products can be manufactured by injection molding or by 3D printing process if rapid prototyping is need. Special additives present in the polymer matrix enable direct electroless metallization only on the surface which was laser activated.
View Article and Find Full Text PDFThe paper presents the effects of biodegradation of polylactide containing natural anti-aging compounds. Polymer containing 0.5; 5 and 10 wt % of coffee, cocoa or cinnamon extracts were subjected to industrial composting for 7, 14, 21 or 28 days.
View Article and Find Full Text PDFIn this study, natural extracts of plant origin were used as anti-aging compounds of biodegradable polymers. Coffee (0.5⁻10 wt%), cocoa, or cinnamon extracts were added to the polylactide matrix.
View Article and Find Full Text PDF