Publications by authors named "Barrat J"

We determined the concentrations of trace elements including Fe, Al, rare earth elements and Y (REY), in Ascophyllum nodosum, one of the most abundant brown macroalgae in the North Atlantic. Samples were collected in the Bay of Brest (Brittany, France) and in the estuary of its main contributing river. The Y/Ho, Al/Ga, and Zr/Hf ratios display values distinctive from seawater, but similar to the continental crust; an observation which we show cannot be explained by the incorporation of terrigenous particles, nor inorganic colloids.

View Article and Find Full Text PDF

We report on the experimental realization and characterization of a qubit analog with semiconductor exciton-polaritons. In our system, a polaritonic condensate is confined by a spatially patterned pump laser in an annular trap that supports energy-degenerate vortex states of the polariton superfluid. Using temporal interference measurements, we observe coherent oscillations between a pair of counter-circulating vortex states coupled by elastic scattering of polaritons off the laser-imprinted potential.

View Article and Find Full Text PDF

It appeared certain that elastin condensates retain liquid-like properties. However, a recent experimental study demonstrated that their aggregate states might depend on the length of hydrophobic domains. To gain microscopic insight into this behavior, we employ atomistic modeling to assess the conformational properties of hydrophobic elastin-like polypeptides (ELPs).

View Article and Find Full Text PDF
Article Synopsis
  • The composition of volatile elements varies widely among planetary bodies like Earth, Mars, and the Moon, sparking debates about the processes behind these variations.
  • Howardites-eucrites-diogenites (HED) meteorites, likely from asteroid 4-Vesta, provide valuable information about the depletion of volatiles in the Solar System.
  • The study reveals that the zinc isotopic composition in diogenites indicates minimal outer solar system influence on 4-Vesta's volatiles, suggesting a history of global evaporation followed by partial recondensation, impacting the volatile content of planetary bodies.
View Article and Find Full Text PDF
Article Synopsis
  • Soft amorphous materials, like clays and gels, are common viscoelastic solids that can transform from solid to liquid under deformation, altering their microstructure.
  • A workshop at the Lorentz Center in Leiden from January 9 to 13, 2023, focused on this yielding transition in these materials.
  • The resulting manuscript highlights key insights and open questions from discussions at the workshop, pointing to future experimental and theoretical challenges in the field.
View Article and Find Full Text PDF

We monitor the orbital degree of freedom of exciton-polariton condensates confined within an optical trap and unveil the stochastic switching of persistent annular polariton currents under pulse-periodic excitation. Within an elliptical trap, the low-lying in energy polariton current states manifest as a two-petaled density distribution with a swirling phase. In the stochastic regime, the density distribution, averaged over multiple excitation pulses, becomes homogenized in the azimuthal direction.

View Article and Find Full Text PDF

This paper summarizes the main guidelines for representing rare earth element (REE) abundance patterns, along with a review of the common mistakes or omissions that can alter REE plots and bias interpretations. It is specifically designed for ecotoxicologists and biologists, for whom the study of these elements has become an important field of research in recent years. Prior to applying REE diagrams to the study of living organisms, it is important to understand the rationale that led geochemists and cosmochemists to develop them.

View Article and Find Full Text PDF

Rare Earth Elements (REE) and several trace elements abundances in mussel's shells collected along the St. Lawrence River, the Estuary, and the Gulf of St. Lawrence (EGSL) reveal coherent chemical variations, with a sharp contrast between freshwater and seawater bivalves.

View Article and Find Full Text PDF

Beyond well-documented confinement and surface effects arising from the large internal surface and severely confining porosity of nanoporous hosts, the transport of nanoconfined fluids remains puzzling in many aspects. With striking examples such as memory, i.e.

View Article and Find Full Text PDF

In this work using computer simulations of 3D model of dense disordered solids we show, for the first time, the appearance of shear localization in the stationary flow under homogeneous driving conditions. To rationalize our simulation results we develop a continuum model, that couples the dynamics of the local flow to the evolution of a kinetic temperature field related to the local inertial dynamics. Our model predicts that the coupling of the flow field to this additional destabilizing field appears only as a necessary condition for shear localization, a minimum system size is necessary to accommodate the flow instability.

View Article and Find Full Text PDF

Point of care ultrasound (POCUS) has become a common practice in prehospital care over the last 10 years. There is lack of literature on its use and governance structure in United Kingdom (UK) prehospital care services. We aimed to survey the use, governance of prehospital POCUS among UK prehospital services and perceptions of clinicians and services regarding its utility and barriers to its implementation.

View Article and Find Full Text PDF
Article Synopsis
  • Elastin-like peptides (ELPs) are synthetic proteins mimicking elastin, exhibiting unique behaviors based on temperature and concentration due to their lower critical solution temperature (LCST).
  • In molecular dynamics simulations of the GVG(VPGVG) sequence, a change in interaction between peptides is observed from repulsive to attractive as temperature increases, demonstrating LCST-like properties.
  • Additionally, the study finds that higher temperatures and peptide concentrations lead to slowed movements and the formation of aggregates with distinct structural configurations, highlighting the influence of valine residues.
View Article and Find Full Text PDF

The crowded environment of biological systems such as the interior of living cells is occupied by macromolecules with a broad size distribution. This situation of polydispersity might influence the dependence of the diffusive dynamics of a given tracer macromolecule in a monodisperse solution on its hydrodynamic size and on the volume fraction. The resulting size dependence of diffusive transport crucially influences the function of a living cell.

View Article and Find Full Text PDF

Quasi-two-dimensional (quasi-2D) colloidal hard-sphere suspensions confined in a slit geometry are widely used as two-dimensional (2D) model systems in experiments that probe the glassy relaxation dynamics of 2D systems. However, the question to what extent these quasi-2D systems indeed represent 2D systems is rarely brought up. Here, we use computer simulations that take into account hydrodynamic interactions to show that dense quasi-2D colloidal bi-disperse hard-sphere suspensions exhibit much more rapid diffusion and relaxation than their 2D counterparts at the same area fraction.

View Article and Find Full Text PDF

Rabies is a deadly viral disease present mainly in low-income countries of Africa and Asia. Dogs are the main reservoir and the source of human deaths. Mass vaccination campaigns of dogs are pivotal to achieve rabies elimination.

View Article and Find Full Text PDF

We investigate the temperature dependence of thermodynamic (density and isobaric heat capacity), dynamical (self-diffusion coefficient and shear viscosity), and dielectric properties of several water models, such as the commonly employed TIP3P water model, the well-established four-point water model TIP4P-2005, and the recently developed four-point water model TIP4P-D. We focus on the temperature range of interest for the field of computational biophysics and soft matter (280-350 K). The four-point water models lead to a spectacularly improved agreement with experimental data, strongly suggesting that the use of more modern parameterizations should be favored compared to the more traditional TIP3P for modeling temperature-dependent phenomena in biomolecular systems.

View Article and Find Full Text PDF

The formation and differentiation of planetary bodies are dated using radioactive decay systems, including the short-lived 146Sm-142Nd (T½ = 103 or 68 Ma) and long-lived 147Sm-143Nd (T½ = 106 Ga) radiogenic pairs that provide relative and absolute ages, respectively. However, the initial abundance and half-life of the extinct radioactive isotope 146Sm are still debated, weakening the interpretation of 146Sm-142Nd systematics obtained for early planetary processes. Here, we apply the short-lived 26Al-26Mg, 146Sm-142Nd, and long-lived 147Sm-143Sm chronometers to the oldest known andesitic meteorite, Erg Chech 002 (EC 002), to constrain the Solar System initial abundance of 146Sm.

View Article and Find Full Text PDF

In Europe, animal tuberculosis (TB) due to involves multi-host communities that include cattle and wildlife species, such as wild boar (), badgers () and red deer (). Red fox () infections have also been recently reported in some TB endemic regions in the Iberian Peninsula and France, with some of the infected animals shedding in urine and feces. In order to understand the pathogenesis of infection in foxes and the associated risk of transmission, 12 captive foxes (6 females and 6 males) were inoculated orally with 2 × 10 colony-forming units of a French field isolate of .

View Article and Find Full Text PDF
Article Synopsis
  • The quantum harmonic oscillator is crucial for calculating thermal properties of dielectric crystals at low temperatures through phonons and can be expanded to include more complex scenarios like anharmonic couplings and disordered solids.
  • Path Integral Monte Carlo (PIMC) is an effective method for obtaining thermodynamic quantities without bias, but calculating transport properties such as thermal conductivity using PIMC is more complex and often requires Bayesian methods for accurate data inversion from imaginary to real time.
  • The authors propose improved estimators for current correlations to reduce variance in PIMC data and introduce a new statistical workflow that combines classical and modern methods for better inversion results, demonstrating their approach with various oscillator models to establish a foundation for unbiased quantum calculations of solid transport properties.
View Article and Find Full Text PDF

In order to propose an optimal analytical procedure specific to ferromanganese (Fe-Mn) oxides, we investigated different modes of data acquisition using inductively coupled plasma mass spectrometry (ICP-MS). The results of trace element and Rare Earth Element (REE) determination in eight Fe-Mn nodules and crusts (FeMn-1, GSMC-1, GSMC-2, GSMC-3, GSPN-2, GSPN-3, NOD-A-1 and NOD-P-1) are presented here. The analytical procedure involves chemical dissolution of the Fe-Mn oxides and addition of a thulium (Tm) spike.

View Article and Find Full Text PDF
Article Synopsis
  • Natural biological surfaces, like hair and skin, have unique properties that affect how water-based molecules, such as those in shampoos and cleansers, adhere to them.
  • This study uses molecular dynamics simulations to explore how flexible homopolymers interact with chemically diverse substrates that mimic hair surfaces, focusing on factors like polymer chain length and concentration.
  • Findings reveal that as polymer concentration increases, the structures formed (trains, loops, and tails) change, and the research aims to enhance models for better eco-friendly products in consumer industries.
View Article and Find Full Text PDF