Publications by authors named "Barbara Zanfrognini"

In this work, we investigated the ability of an electrochemical sensor to recognize Cannabis sativa L. samples with different total content of Δ-tetrahydrocannabinol (Δ-THC), determined by the levels of the psychoactive cannabinoid and of its biosynthetic precursor Δ-tetrahydrocannabinolic acid (Δ-THCA), using a multivariate approach. The voltammetric responses recorded with screen-printed electrodes modified with carbon black reflected the compositional differences from the different samples, in terms of cannabinoids of the vegetal material.

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Two electrochemical sensors are proposed here for the first time for the fast screening of cannabinoids in L. plant material (inflorescences). The accurate control of cannabinoid content is important for discriminating between recreational, illegal, and fibre-type samples, which differ mainly according to the amount of Δ-tetrahydrocannabinol (Δ-THC) and Δ-tetrahydrocannabinolic acid (Δ-THCA).

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Reusable Sonogel-Carbon electrodes containing carbon black (SNGC-CB) have been used for the electrochemical analysis of caffeic acid (CA) in real matrices. Measurements were firstly performed in standard solutions, in which SNGC-CB electrodes allowed the electrochemical determination of CA with high sensitivity and low limit of detection, equal to 0.76 μM.

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Silica-based electrodes which permanently include a graphite/Au nanoparticles composite were tested for non-enzymatic detection of glucose and fructose. The composite material showed an effective electrocatalytic activity, to achieve the oxidation of the two analytes at quite low potential values and with good linearity. Reduced surface passivation was observed even in presence of organic species normally constituting real samples.

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A glassy carbon electrode chemically modified with a carbon black coating is proposed here for the rapid and portable determination of cannabidiol (CBD) in a commercial Cannabis seed oil and in fibre-type Cannabis sativa L. leaves. The mechanism of CBD oxidation was studied in relation to simpler phenyl derivatives bearing the same electroactive group, namely resorcinol and 2-methylresorcinol.

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The control of the noble metal concentration is crucial in order to increase the efficiency of hydrometallurgic processes in mining and in the recovery of precious materials from electronic waste. The present study is devoted to the development of an effective procedure for the quantification of Au(III) species dissolved in aqueous solutions, similar real complex matrices included. In particular, a novel electrode system based on Ti has been studied.

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n instrument for the automatic quantification of glycerol in grapes has been developed. We verify here that this analyte can be used as a benchmark of a serious disease affecting the grapevines, namely Botrytis cinerea. The core of the instrument is an amperometric biosensor consisting of a disposable screen printed electrode, generating the analytical signal thanks to a bi-enzymatic process involving glycerol dehydrogenase and diaphorase.

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