In Situ Construction of Specific SEI Layer Affords Effective Prelithiation.

Silicon-based anodes have been attracting attention due to their high theoretical specific capacity, but their low initial Coulombic efficiency (ICE) seriously hinders their commercial application. Direct contact prelithiation is considered to be one of the effective means of solving this problem. By means of prelithiation, a specific solid electrolyte interphase (SEI) was constructed, which inhibited the volume expansion of the SiO/C composite anode during prelithiation and reduced the local current generated when the lithium source was in contact with the anode.

Green Synthesis of Dual Carbon Conductive Network-Encapsulated Hollow SiO Spheres for Superior Lithium-Ion Batteries.

Designing hollow/porous structure is regarded as an effective approach to address the dramatic volumetric variation issue for Si-based anode materials in Li-ion batteries (LIBs). Pioneer studies mainly focused on acid/alkali etching to create hollow/porous structures, which are, however, highly corrosive and may lead to a complicated synthetic process. In this paper, a dual carbon conductive network-encapsulated hollow SiO (DC-HSiO ) is fabricated through a green route, where polyacrylic acid is adopted as an eco-friendly soft template.

In situ synthesis of porous Si dispersed in carbon nanotube intertwined expanded graphite for high-energy lithium-ion batteries.

Silicon (Si) is perceived as one of the most promising anode materials for next-generation lithium-ion batteries (LIBs). For its practical application, superior electrochemical properties, low cost and scalable production are highly required. Herein, we synthesize a carbon nanotube intertwined expanded graphite/porous Si (CNT/EG/pSi) composite through the in situ magnesiothermic reduction method, where porous Si nanoparticles (NPs) are dispersed in the interspaces constructed by EG sheets, with CNTs intertwined throughout the composite, connecting Si NPs and EG sheets.