To study the effect of different cationic polyacrylamide organic dehydrating agents on sludge dewatering performance, eight commercially available cationic polyacrylamides of the same series with different properties were used. Based on the different cationic degree, they were named 9101, 9102, 9103, 9104, 9106, 9108, 9110, and 9112, respectively. Their properties were characterized by instruments and chemical analysis, and the indexes of sludge after treatment were also measured.
View Article and Find Full Text PDFPreferential removal of phosphate from aqueous was conducted by a novel biomass-based nanocomposite (EP-N-Zr) with encapsulated hydrous zirconium oxide, and the biopolymer EP-N-Zr features were described. EP-N-Zr exhibited high selective sequestration toward phosphate when humic acid or other competing anions (Cl, SO, NO, ClO) coexisted at relatively high levels. Such excellent performance of EP-N-Zr was attributed to its specific two site structures; the embedded HZO nanoparticles and quaternary ammonia groups [N(CHCH)Cl] bonded inside the biomass-Enteromorpha prolifera, which facilitated preferable capture towards phosphate through specific affinity and nonspecific preconcentration of phosphate ions on the basis of the ion exchange, respectively.
View Article and Find Full Text PDFA novel granulation strategy by introducing magnetic nanoparticles (MNPs) into activated sludge system was investigated in this study. The study of the physicochemical characteristics (appearances, sizes, sludge volume index, and chemical oxygen demand) demonstrated that MNPs could decrease the granulation time and improve the retention of biomass, meanwhile enhanced the compact structure of the granules. The secretion and functional groups especially OH and CO of extracellular polymeric substances (EPS) also had significant changes under the long-term influence of MNPs.
View Article and Find Full Text PDFA cellulose-rich biomass was modified as a new amphoteric sorbent to eliminate toxic Cu(II) and Cr(VI) from wastewater. The product (WSCA, which stands for modified wheat straw containing both cationic and anionic characters) presents high sorption capacities for the two ions which was evidenced by the comparison with unmodified wheat and other similar samples. Kinetic data and sorption equilibrium isotherms were conducted in batch process.
View Article and Find Full Text PDFBackground: Dosing environment-friendly polymer as coagulant aids is an encouraging method in water treatment to obtain desirable floc characteristics. Sodium alginate (SA) was used as the coagulant aid for synthetic humic acid (HA) water treatment to investigate the effect on flocs characteristics and ultrafiltration (UF) membrane fouling.
Results: When SA content was 0.
Polyferric chloride (PFC) and poly (epichlorohydrin-dimethylamine) [P(EPI-DMA)] were applied as raw materials to prepare a novel inorganic-organic flocculant [PFC-P(EPI-DMA)] with various intrinsic viscosities (eta), basicity (B, OH/Fe molar ratio), and organic component fractions [omega(E)]. The PFC-P(EPI-DMA) prepared was then evaluated for the coagulation treatment of synthetic active dying wastewater and simulated ground water. Effects of B, and omega (E) on the Fe speciation distribution and coagulation performance of PFC-P(EPI-DMA) were comparatively examined as a function of coagulant dosage.
View Article and Find Full Text PDFIn this paper, potato starch wastewater as culture medium was treated by the oleaginous yeast Lipomyces starkeyi to biosynthesize microbial lipid. The result indicated that carbon source types, carbon source concentration, nitrogen source types, nitrogen source concentration, inoculum size, and cultivation time all had a significant effect on cell growth and microbial lipid accumulation in batch cultures. A measure of 120 g/L of glucose concentration, 3.
View Article and Find Full Text PDFSludge-based activated carbon (SAC) was prepared from paper mill sewage sludge by physical activation with steam for wastewater treatment in this study. The effects of preparation variables, including carbonization temperature, carbonization time, activation temperature and activation time, on iodine number and yield were investigated through orthogonal experiments. The influences of washing by deionized water and acid on the characteristics and adsorption capacities of SAC for phosphate, methylene blue and reactive red 24 were also studied.
View Article and Find Full Text PDFA cationic organic flocculant epichlorohydrin-dimethylamine (EPI-DMA) was employed for the treatment of acid and direct dye. The study aims at investigating the flocculation performance of EPI-DMA for the model dye, and corresponding floc aggregation properties, which were determined by jar test and photometric dispersion analysis, respectively. The interactions between cationic flocculant and anionic dye were investigated through spectra analysis.
View Article and Find Full Text PDFThe monosodium glutamate (MSG) wastewater as a medium was treated by Lipomyces starkeyi to produce microbial lipid in the study. The effect of related factors (initial glucose concentration, inoculation concentration, initial culture pH, and cultivation time) on biomass, lipid production and lipid content was discussed, respectively. According to the experiments, the optimal fermentation conditions were determined: addition of 80g/L glucose, 10% inoculation concentration, initial pH about 5.
View Article and Find Full Text PDFA new cellulosic amine-crosslinked copolymer was prepared after the amination reaction with cotton stalk peel (CSP). The physicochemical characteristics of amine-crosslinked cotton stalk peel (AC-CSP) and raw CSP were determined after the surface analysis (including specific surface area, micropore volume and SEM), zeta potential analysis and spectrum analysis (FTIR and Raman spectrum). The sorption properties of AC-CSP for Cr(VI) were evaluated in the static, column sorption and desorption tests.
View Article and Find Full Text PDFDeveloping a novel biosorbent with high capacity is crucial to remove dyes from waters in an efficient way. This study demonstrated that porous anaerobic granular sludge could be grafted with polyethylenimine (PEI), which definitely improved the sorption capacity towards Acid Red 18 (AR18) removal. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) study revealed that the PEI modification introduced a large number of amino groups on the surface of sludge, and the amino groups played an important role in the adsorption of dye molecule.
View Article and Find Full Text PDFThe possibility to introduce the exotic anammox sludge to seed the pilot-scale anammox granular reactor and its fast start-up for treating high nitrogen concentration wastewater were evaluated in this study. The reactor was started up successfully in two weeks; in addition, high nitrogen removal was achieved for a long period. Stoichiometry molar ratios of nitrite conversion and nitrate production to ammonium conversion were calculated to be 1.
View Article and Find Full Text PDFThe nitrate removal process was evaluated using a fixed-bed column packed with amine-crosslinked wheat straw (AC-WS). Column sorption and desorption characteristics of nitrate were studied extensively. Solid-state (13)C NMR and zeta potential analysis validated the existence of crosslinked amine groups in AC-WS.
View Article and Find Full Text PDFColloids Surf B Biointerfaces
February 2011
The biosorption characteristics of cations and anions from aqueous solution using polyethylenimine (PEI) modified aerobic granules were investigated. Fourier transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis exhibit the presence of PEI on the granule surface. Compared with the raw granule, the modified aerobic granules with PEI showed a significant increase in sorption capacity for both metal ions.
View Article and Find Full Text PDFThe application of AlCl3, Al2 (SO4)3 and poly-aluminum chloride (PAC) in humic acid-kaolin simulated water was studied in this article. It is intended to discuss the relationship among coagulation effect of Al-based coagulants in humic acid-kaolin simulated water and content and speciation of residual aluminum. It was found that, the turbidity removal efficiency and UV254 removal efficiency could reach about 90% at the tested dosage.
View Article and Find Full Text PDFTwo types of inorganic polymer coagulants, polyferric chloride (PFC) and polyaluminum chloride (PAC), were chosen to treat the Yellow River water. Different dosages were investigated in order to investigate the turbidity, UV24, DOC and permanganate index removal efficiency and their coagulation mechanisms based on the Zeta potentials. The natural organic matter removal by the combination of coagulation and adsorption with powder activated carbon were analyzed based on different coagulant and adsorbent dosages and dosing orders.
View Article and Find Full Text PDFTo develop the agricultural by-product adsorbent that possesses anionic exchangeable function, the performance of a new anion exchanger prepared from wheat straw (WS) was evaluated in this study. Wheat straw anion exchanger (WS-AE) was prepared by the grafting of aminated intermediate onto WS. Results indicate that reaction time and temperature in the chemical modification process both affected the preparation of aminated intermediate and WS-AE.
View Article and Find Full Text PDFGranular anammox reactors usually adopted anaerobic/aerobic granules as source sludge, in which the washout of other species and enrichment of anammox biomass were very slow because of the competition of the coexisting bacteria. In this study, inactive methanogenic granules were proved to be suitable for rapid anammox granulation under high nitrogen concentrations by investigating their interaction with anammox bacteria. The start-up nitrite concentration was significantly higher than the published toxic level for anammox bacteria and other lab-scale studies.
View Article and Find Full Text PDFWater Environ Res
April 2010
The use of modified giant reed (MGR) as an adsorbent to remove phosphate from an aqueous solution was investigated. The dosage of MGR, pH of the phosphate solution, thermodynamics, and the effects of several factors on kinetics (concentration of phosphate solution, solution temperature, and shaking speed) were studied in batch experiments. The results showed that MGR was particularly effective to remove phosphate and that the effective pH range for the phosphate removal was between 4 and 9.
View Article and Find Full Text PDFRemoval of Acid Red 73 (AR 73) and Reactive Red 24 (RR 24) onto modified wheat straw (MWS) from aqueous solutions was investigated. Sorption experiments were carried out as function of MWS dosage, contact time, initial concentration, pH and temperature. Characterizations of MWS were measured and a mass of amine groups were observed in the framework of MWS.
View Article and Find Full Text PDFDisintegrated aerobic granules (DAG) as an effective biosorbent had great potential to remove Cu(II) from aqueous solution. The effects of solution pH value, contact time, initial Cu(II) concentration on the biosorption were investigated. Kinetic studies indicate that pseudo-second-order model with correlation coefficients of 0.
View Article and Find Full Text PDFThe adsorption properties and mechanisms of a cationic-polymer/bentonite complex (EPI-DMA/bentonite), prepared from polyepicholorohydrin-dimethylamine and bentonite, for non-ionic dyes (Disperse Blue SBL and Vat Scarlet R) and anionic dyes (Reactive Violet K-3R and Acid Dark Blue 2G) were investigated in this study. The solution pH, presence of salt and surfactant can significantly affect the dye removal efficiency. The equilibrium data were analyzed using the Langmuir and Freundlich models.
View Article and Find Full Text PDFInteractions of Cu2+, Ni2+ on humic acid and the mixture adsorbent of humic acid and bentonite were studied. The effects of contact time, initial pH and temperature were determined. The removal rate of the metal ions increased with increasing contact time.
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