Ca(II) doped β-InS hierarchical structures for photocatalytic hydrogen generation and organic dye degradation under visible light irradiation.

Hierarchical structures assembled by two-dimensional (2D) nanosheets could inherit the characteristics of nanosheets and acquire additional advantages from the unique secondary architectures, which would have important influences on the photocatalytic properties of semiconductor nanomaterials. In this work, we successfully synthesized Ca(II) doped β-InS hierarchical structures stacked by thin nanosheets by a simple solution chemical process. The effects of reaction temperature and Ca concentration on the size and morphology of the products were systematically investigated.

Room temperature synthesis of hollow CdMoO(4) microspheres by a surfactant-free aqueous solution route.

Hollow cadmium molybdate microspheres have been successfully prepared via a template-free aqueous solution method with the assistance of NaCl at room temperature. The structure and morphology of the CdMoO(4) hollow microspheres were characterized by X-ray diffraction, field-emission scanning electron microscopy, and transmission electron microscopy. The microspheres have diameters of 3-6 microm and hollow interiors of 2-3 microm.