Photocatalytic activity of TiO2 and zeolites supported TiO2 were investigated using propoxur as a model pollutant. Hbeta, HY and H-ZSM-5 zeolites were examined as supports for TiO2. Hbeta was chosen as the TiO2 support based on the adsorption capacity of propoxur on these zeolites (Hbeta>HY=H-ZSM-5).
View Article and Find Full Text PDFJ Nanosci Nanotechnol
September 2007
TiO2 and Gd3+ doped TiO2 nanoparticles were prepared by sol-gel method and the materials were characterized by XRD, TEM, SEM-EDX, BET, FT-IR, UV-Vis absorption, and Raman spectral analysis. The photocatalytic activity of nano TiO2 and Gd/TiO2 nanoparticles was evaluated using a model pollutant propoxur, a carbamate pesticide, in a batch type UV photoreactor. The results revealed higher photocatalytic activity for Gd/TiO2 nanoparticles than both TiO2 nanoparticles and commercial TiO2 (Degussa P-25).
View Article and Find Full Text PDFThe photocatalytic degradation of carbofuran (2,3-dihydro-2,2-dimethylbenzofuran-7-yl methylcarbamate) was investigated in an aqueous solution using Degussa P-25 TiO2 and ZnO as photocatalysts. The progress of degradation was monitored using TOC analyzer, HPLC, GC-MS and UV-vis spectrophotometer. The effects of various experimental parameters such as initial concentration of carbofuran, pH of the solution, catalyst loading and light intensity were systematically studied in order to achieve maximum degradation efficiency.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
August 2006
Nitrogen doped titania was prepared by low temperature sol-gel method using titanium precursor and nitrogen containing bases like triethylamine and tetramethyl ammonium hydroxide compounds. The materials were characterized by XRD, BET, SEM, XPS, DRS-UV, and FT-IR techniques. DRS-UV study substantially indicates shift of the absorption edge of TiO2 to lower energy region.
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View Article and Find Full Text PDFPt, Au and Pd deposited TiO2 have been prepared and characterised by surface analytical methods such as surface area, XRD, and scanning electron micrograph and photophysical characterisation by diffuse reflectance spectroscopy. The photocatalytic activity of the doped catalysts was ascertained by the photo-oxidation of leather dye, acid green 16 in aqueous solution illuminated with low-pressure mercury lamp ( approximately 254 nm). The effect of metal contents on the photocatalytic activity was investigated.
View Article and Find Full Text PDFPhotocatalytic degradation of monocrotophos has been carried out in a slurry type batch reactor. The reaction variables were optimised to obtain maximum degradation efficiency. The degradation rate of monocrotophos is significantly higher for acidic solutions than for alkaline solutions.
View Article and Find Full Text PDFThe photocatalytic degradation of three commercial textile dyes with different structure has been investigated using TiO(2) (Degussa P25) photocatalyst in aqueous solution under solar irradiation. Experiments were conducted to optimise various parameters viz. amount of catalyst, concentration of dye, pH and solar light intensity.
View Article and Find Full Text PDFActivated carbon prepared from rubber seed coat (RSCC), an agricultural waste by-product, has been used for the adsorption of phenol from aqueous solution. In this work, adsorption of phenol on rubber seed coat activated carbon has been studied by using batch and column studies. The equilibrium adsorption level was determined to be a function of the solution pH, adsorbent dosage and contact time.
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