Quantum computing requires a universal set of gate operations; regarding gates as rotations, any rotation angle must be possible. However a real device may only be capable of B bits of resolution, i.e.
View Article and Find Full Text PDFSolid State Nucl Magn Reson
August 2016
The basic MQMAS sequence consists of two hard pulses, one excites the equilibrium population to MQ (Multiple Quantum) coherence, and the other converts back to detectable coherence after some evolution time t1 (Medek et al., 1995). Unfortunately the MQ excitation and conversion processes are very inefficient due to the nonlinear nature of MQ processes.
View Article and Find Full Text PDFTuning and matching of NMR probes is necessary for many fields of NMR application including temperature dependent NMR, thermoporometry and cryoporometry, or when significantly different types of samples are measured in automation using sample changers. Mismatch of the probe is an especially critical issue in the case of high magnetic fields, polar or ionic solvents, or extreme thermal conditions. Careful tuning is particularly important for quantitative NMR measurements.
View Article and Find Full Text PDFConcerning many former liquid or hybrid liquid/solid NMR consoles, the built in Analog-to-Digital Converters (ADCs) are incapable of digitizing the fids at sampling rates in the MHz range. Regarding both strong anisotropic interactions in the solid state and wide chemical shift dispersion nuclei in solution phase such as (195)Pt, (119)Sn, (207)Pb etc., the spectrum range of interest might be in the MHz range.
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