The synthesis of fructose-based surfactants.

This study describes the synthesis of a new class of surfactants that is based on the bioderived building blocks fructose, fatty acid methyl esters (FAME), and hydroxy propionitrile (cyanoethanol, 3-HP). The synthesis is scalable, is carried out at ambient conditions, and does not require chromatography. The produced surfactants have excellent surfactant properties with critical micelle concentrations and Krafft points comparable to current glucose-based surfactants.

A molecular motor from lignocellulose.

Lignin is the largest natural source of functionalized aromatics on the planet, therefore exploiting its inherent structural features for the synthesis of aromatic products is a timely and ambitious goal. While the recently developed lignin depolymerization strategies gave rise to well-defined aromatic platform chemicals, the diversification of these structures, especially toward high-end applications is still poorly addressed. Molecular motors and switches have found widespread application in many important areas such as targeted drug delivery systems, responsive coatings for self-healing surfaces, paints and resins or muscles for soft robotics.

Development of 'Lignin-First' Approaches for the Valorization of Lignocellulosic Biomass.

Currently, valorization of lignocellulosic biomass almost exclusively focuses on the production of pulp, paper, and bioethanol from its holocellulose constituent, while the remaining lignin part that comprises the highest carbon content, is burned and treated as waste. Lignin has a complex structure built up from propylphenolic subunits; therefore, its valorization to value-added products (aromatics, phenolics, biogasoline, etc.) is highly desirable.

Selective Coupling of Bioderived Aliphatic Alcohols with Acetone Using Hydrotalcite Derived Mg-Al Porous Metal Oxide and Raney Nickel.

Fermentation of sugars to the so-called ABE mixture delivers a three component mixture of shorter chain oxygenates: acetone, -butanol and ethanol. In order to convert these into liquid transportation fuels that are analogous to the currently used fossil energy carriers, novel catalytic chain elongation methods involving C-C bond formation are desired. Herein we report on a simple, non-noble-metal-based method for the highly selective coupling of 1-butanol and acetone into high molecular weight (C7-C11) ketones, as well as ABE mixtures into (C5-C11) ketones using the solid base Mg-Al-PMO in combination with small amount of Raney nickel.

Bright Side of Lignin Depolymerization: Toward New Platform Chemicals.

Lignin, a major component of lignocellulose, is the largest source of aromatic building blocks on the planet and harbors great potential to serve as starting material for the production of biobased products. Despite the initial challenges associated with the robust and irregular structure of lignin, the valorization of this intriguing aromatic biopolymer has come a long way: recently, many creative strategies emerged that deliver defined products via catalytic or biocatalytic depolymerization in good yields. The purpose of this review is to provide insight into these novel approaches and the potential application of such emerging new structures for the synthesis of biobased polymers or pharmacologically active molecules.