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View Article and Find Full Text PDFThe present work addresses the limitations by fabricating a wide range of negative electrodes, including metal nitrides/sulfides on a 3D bimetallic conductive porous network (3D-Ni and 3D-NiCo) via a dynamic hydrogen bubble template (DHBT) method followed by vapour phase growth (VPG) process. Among the prepared negative electrodes, the 3D-FeS-FeN/NiCo nanostructure demonstrates an impressive specific capacitance (C) of 1125 F g (2475 mF cm) at 1 A g with 80% capacitance retention over 5000 cycles. Similarly, a 3D-MnP nanostructured positive electrode fabricated via electrodeposition followed by a phosphorization process exhibits a maximum specific capacity (C) of 923.
View Article and Find Full Text PDFThe study presents the binder-free synthesis of mixed metallic organic frameworks (MMOFs) supported on a ternary metal oxide (TMO) core as an innovative three-dimensional (3D) approach to enhance electron transport and mass transfer during the electrochemical charge-discharge process, resulting in high-performance hybrid supercapacitors. The research demonstrates that the choice of organic linkers can be used to tailor the morphology of these MMOFs, thus optimizing their electrochemical efficiency. Specifically, a NiCo-MOF@NiCoO@Ni electrode, based on terephthalic linkers, exhibits highly ordered porosity and a vast internal surface area, achieving a maximum specific capacity of 2320 mC cm, while maintaining excellent rate capability and cycle stability.
View Article and Find Full Text PDFElectrochemical energy storage is a current research area to address energy challenges of the modern world. The CuFeSnS/PVP/rGO-decorated nanocomposite using PVP as the surface ligand was explored in a simple one-step solvothermal route, for studying their electrochemical behavior by designing asymmetric hybrid supercapacitor devices. The full cell three-electrode arrangements delivered 748 C/g (62.
View Article and Find Full Text PDFHerein, we report a novel, low-temperature solvothermal method to grow 3D-Bi2O3 flower-like microspheres on Ti substrates as a binder-free negative electrode for supercapacitor applications. The Bi2O3/Ti electrode showed an areal capacitance of 1.65 F cm-2 at 4 mA cm-2.
View Article and Find Full Text PDFComparative investigation of the electrochemical oxygen evolution reaction (OER) activity for clean energy production was performed by fabricating three different electrodes, namely, NiSe, CoSe, and CoNiSe, synthesized by hydrothermal treatment. Cubic, orthorhombic, and hexagonal structures of NiSe, CoSe, and CoNiSe were confirmed by X-ray diffraction (XRD) and also by other characterization studies. Perfect nanospheres, combination of distorted nanospheres and tiny nanoparticles, and sharp-edge nanostructures of NiSe, CoSe, and CoNiSe were explored by surface morphological images.
View Article and Find Full Text PDFElectrochemical energy storage devices (EESs) play a crucial role for the construction of sustainable energy storage system from the point of generation to the end user due to the intermittent nature of renewable sources. Additionally, to meet the demand for next-generation electronic applications, optimizing the energy and power densities of EESs with long cycle life is the crucial factor. Great efforts have been devoted towards the search for new materials, to augment the overall performance of the EESs.
View Article and Find Full Text PDFSensors (Basel)
May 2019
A copper sulfide nanoflakes-decorated carbon nanofragments-modified glassy carbon electrode (CuS-CNF/GCE) was fabricated for the electrocatalytic differentiation and determination of hydroquinone (HQ) and catechol (CC). The physicochemical properties of the CuS-CNF were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and Raman spectroscopy. The electrocatalytic determination of HQ and CC over the CuS-CNF/GCE was evaluated by cyclic voltammetry and differential pulse voltammetry.
View Article and Find Full Text PDFA hybrid nanofibrous mat consisting of polyurethane, dextran, and 10 wt % of biopigment (i.e., pyocyanin) was facilely fabricated using a direct-conventional electrospinning method.
View Article and Find Full Text PDFCell Commun Adhes
December 2018
The objective of this study was to synthesize and characterize novel polyurethane (PU)-nanofiber coated with l-arginine by electrospinning technique. This study determined whether l-arginine conjugated with PU-nanofiber could stimulate cell proliferation and prevent HO-induced cell death in satellite cells co-cultured with fibroblasts isolated from Hanwoo (Korean native cattle). Our results showed that l-arginine conjugated with PU nanofiber could reduce cytotoxicity of co-cultured satellite cells.
View Article and Find Full Text PDFWire type supercapacitors with high energy and power densities have generated considerable interest in wearable applications. Herein, we report a novel NiCoS-decorated 3D, porous Ni film@Ni wire electrode for high performance supercapacitor application. In this work, a facile method is introduced to fabricate a 3D, porous Ni film deposited on a Ni wire as a flexible electrode, followed by decoration with NiCoS as an electroactive material.
View Article and Find Full Text PDFA lightweight, flexible, cost-effective, and robust, single-electrode-based Smart Seat-Triboelectric Nanogenerator (SS-TENG) is introduced as a promising eco-friendly approach for harvesting energy from the living environment, for use in integrated self-powered systems. An effective method for harvesting biomechanical energy from human motion such as walking, running, and sitting, utilizing widely adaptable everyday contact materials (newspaper, denim, polyethylene covers, and bus cards) is demonstrated. The working mechanism of the SS-TENG is based on the generation and transfer of triboelectric charge carriers between the active layer and user-friendly contact materials.
View Article and Find Full Text PDFSci Rep
February 2016
A new paradigm in cancer theranostics is enabled by safe multifunctional nanoplatform that can be applied for therapeutic functions together with imaging capabilities. Herein, we develop a multifunctional nanocomposite consisting of Graphene Oxide-Iron Oxide -Doxorubicin (GO-IO-DOX) as a theranostic cancer platform. The smart magnetic nanoplatform acts both as a hyperthermic agent that delivers heat when an alternating magnetic field is applied and a chemotherapeutic agent in a cancer environment by providing a pH-dependent drug release to administer a synergistic anticancer treatment with an enhanced T2 contrast for MRI.
View Article and Find Full Text PDFWe demonstrate a flexible piezoelectric nanogenerator (PNG) constructed using a hybrid (or composite) film composed of highly crystalline BaTi(1-x)Zr(x)O3 (x = 0, 0.05, 0.1, 0.
View Article and Find Full Text PDFIn this work, we have fabricated a piezoelectric-driven self-charging supercapacitor power cell (SCSPC) using MnO2 nanowires as positive and negative electrodes and a polyvinylidene difluoride (PVDF)-ZnO film as a separator (as well as a piezoelectric), which directly converts mechanical energy into electrochemical energy. Such a SCSPC consists of a nanogenerator, a supercapacitor, and a power-management system, which can be directly used as a power source. The self-charging capability of SCSPC was demonstrated by mechanical deformation under human palm impact.
View Article and Find Full Text PDFACS Appl Mater Interfaces
February 2015
We report the gate-tunable photoresponse of a defective graphene over the ultraviolet (UV) and the visible light illumination, where the defect was generated by plasma irradiation. Plasma induced Dirac point shift indicates the p-doping effect. Interestingly the defective-graphene field effect transistor (defective-GFET) showed a negative shift upon UV illumination, whereas the device showed a positive shift under visible light illumination, along with the change in the photocurrent.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2014
In this study, we developed an innovative, flexible, organic-inorganic hybrid composite nanogenerator, which was used to drive a self-powered microwire-based pH sensor. The hybrid composite nanogenerator was fabricated using ZnO nanowire and piezoelectric polymer poly(vinylidene fluoride), through a simple, inexpensive solution-casting technique. The fabricated hybrid composite nanogenerator delivered a maximum open-circuit voltage of 6.
View Article and Find Full Text PDFACS Appl Mater Interfaces
July 2013
We report the electronic characteristics of an avant-garde graphene-field-effect transistor (G-FETs) based on ZnO microwire as top-gate electrode with self-induced dielectric layer. Surface-adsorbed oxygen is wrapped up the ZnO microwire to provide high electrostatic gate-channel capacitance. This nonconventional device structure yields an on-current of 175 μA, on/off current ratio of 55, and a device mobility exceeding 1630 cm(2)/(V s) for holes and 1240 cm(2)/(V s) for electrons at room temperature.
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