A convenient, non-toxic, and low-cost tin dioxide (SnO)/nickel oxide (NiO)/reduced graphene oxide (rGO) nanocatalytic electrode was investigated, which can effectively promote the hydrogen evolution reaction and can also be used to construct a sensitive winter wheat cold-tolerant RNA sensor. Due to the good synergy and photocurrent generation between SnO and NiO, which accelerates the electron transfer and catalyzes the hydrolysis reaction, the resultant data for the hydrogen evolution reaction in alkaline environment of this material are very impressive, with cathodic current densities of up to 10 mA cm. The marvelous heterostructures and photovoltaic properties form a signal amplification system, which enables the nanocomposites to have an excellent linear sensitivity in low-concentration RNA solutions.
View Article and Find Full Text PDFWith the increasing demand for fruits and vegetables in the market, the development of cold chain logistics has put forward higher requirements for the quality of fruits and vegetables in storage. To ensure the freshness of fruits and vegetables during storage and transportation and avoid unnecessary loss, it is necessary to conduct real-time detection of their odor to ensure their quality. Therefore, based on nano-composite materials combined with Radio Frequency Identification (RFID) technology, this paper designs an integrated RFID sensor that can simultaneously detect temperature, carbon dioxide, and ethanol concentrations.
View Article and Find Full Text PDFDual-functional nanomaterial electrodes have the capability to satisfy the requirements for both sweat analysis and the hydrogen evolution reaction (HER), thereby enabling the integration of electrochemical sensing and hydrogen production. In this study, ZIF-67 cubes are synthesized on nickel foam (NF), while TiO is obtained through an annealing process. Subsequently, the ZIF-67@TiO/MoS nanocomposite is fabricated on nickel foam via a hydrothermal method.
View Article and Find Full Text PDFDefects, which are an unavoidable component of the material preparation process, can have a significant impact on the properties of two-dimensional devices. In this work, we investigated theoretically the effects of different types and positions of point defects on band alignment and transport properties of metallic 1T-phase MoS/semiconducting 2H-phase MoS junctions. We found that the Schottky barriers of junctions depend on the type of defects and their locations while showing anisotropic characteristics along the zigzag and armchair directions of 2H-phase MoS.
View Article and Find Full Text PDFPhys Chem Chem Phys
August 2023
The development of methods for generating pure spin current at the molecular level is vital. In this work, we investigated how the spin-related photocurrent is produced in a cobalt phthalocyanine chain by the photogalvanic effect (PGE). Depending on how the magnetic moments of the left and right halves of the cobalt phthalocyanine chain are arranged, spin current can be generated.
View Article and Find Full Text PDFEfficient electrocatalysts are crucial to water splitting for renewable energy generation. In this work, electrocatalytic hydrogen evolution from Pd nanoparticle-modified graphene nanosheets loaded on ZnO nanowires on nickel foam was studied in an alkaline electrolyte. The high electron mobility stems from the cylindrical ZnO nanowires and the rough surface on the graphene/ZnO nanowires increases the specific surface area and electrical conductivity.
View Article and Find Full Text PDFZnCoO nanosheets were successfully arrayed on a Ni foam surface with graphene using a hydrothermal method followed by annealing treatment; then MnO nanoparticles were electrodeposited on the ZnCoO nanosheets to obtain a synthesized composite binder-free electrode named MnO/ZnCoO/graphene/Ni foam (denoted as MnO/ZnCoO/G/NF). After testing the binder-free composite electrode of MnO/ZnCoO/G/NF cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy testing, we found that it exhibited ultrahigh electrochemical properties, with a high specific areal capacitance of 3405.21 F g under a current density of 2 A g, and wonderful cycling stability, with 91.
View Article and Find Full Text PDFA self-powered nonenzymatic glucose sensor electrode boasts the advantages of both a glucose sensor and fuel cell. Herein, an electrode composed of ZnO-graphene hybrid materials on nickel foam (NF) is prepared by electrodeposition of Pd NPs. The electrode is characterized systematically and the dependence of electrocatalytic oxidation of glucose on the concentrations of KOH and glucose, temperature, and potential limit in the anodic direction is investigated.
View Article and Find Full Text PDFMicroRNAs (miRNAs) are ~20-25 nucleotides non-coding RNAs, which regulated gene expression in the post-transcriptional level. The accurate rate of identifying the start sit of mature miRNA from a given pre-miRNA remains lower. It is noting that the mature miRNA prediction is a class-imbalanced problem which also leads to the unsatisfactory performance of these methods.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
April 2013
Nickel and palladium nanoparticles were finely dispersed on ordered mesoporous silicon microchannels plate (MCP) by electroless plating. The structure and composition of the resulting Ni-Pd/Si MCP were characterized by scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDS). The electrocatalystic properties of Ni-Pd/Si MCP electrode for formaldehyde oxidation have been investigated by cyclic voltammetry.
View Article and Find Full Text PDFA new silicon-based anode suitable for direct ethanol fuel cells (DEFCs) is described. Pd-Ni nanoparticles are coated on Si nanowires (SiNWs) by electroless co-plating to form the catalytic materials. The electrocatalytic properties of the SiNWs and ethanol oxidation on the Pd-Ni catalyst (Pd-Ni/SiNWs) are investigated electrochemically.
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