Structural Engineering-Enabled Joule Heating Effect Cooperated with Capillary Effect Toward Fast Spreading of Droplets for High-Flux Separation of Viscous Emulsion.

Viscous emulsions with poor fluidity and high adhesion are extremely difficult to separate. Herein, high-flux separation of viscous emulsions is realized by developing structural engineered collagen fibers (CFs)-based composite membrane that featured 3D conductive hierarchical fiber structure with the spaced carbon nanofibers (CNFs) and activated carbon (AC) serving as conductive network and competitive adsorption-based demulsifying sites, respectively. The as-designed membrane structure boosts fast spreading of emulsion droplets on membrane surface aided by the synergistic effect of joule heat in situ generated by the spaced CNFs and the capillary effect derived from CFs, which guarantees the full contact of viscous emulsions with the spaced AC for achieving ultra-efficient demulsifying.

Water-oil dual-channels enabled exceptional anti-fouling performances for separation of emulsified oil pollutant.

Oil contamination has been an increasingly concerned environmental issue due to the large quantity of oily wastewater discharged by the industry. The extreme wettability-enabled single-channel separation strategy guarantees efficient separation of oil pollutant from wastewater. However, the ultra-high selective permeability forces the intercepted oil pollutant to form a blocking layer, which weakens the separation capability and slows the kinetics of permeable phase.

Collagen Fiber-Based Advanced Separation Materials: Recent Developments and Future Perspectives.

Separation plays a critical role in a broad range of industrial applications. Developing advanced separation materials is of great significance for the future development of separation technology. Collagen fibers (CFs), the typical structural proteins, exhibit unique structural hierarchy, amphiphilic wettability, and versatile chemical reactivity.

Tannin foam immobilized with ferric ions for efficient removal of ciprofloxacin at low concentrations.

The presence of ciprofloxacin (CIP) in natural water may cause potential threats to the environment. Adsorption is a convenient and efficient method to remove CIP from aqueous solution. Bayberry tannin (BT), a natural polyphenol, has been utilized in the synthesis of tannin foam (TF) due to its abundant polyphenolic hydroxyls to chelate with metal ions.

Insights into Regional Wetting Behaviors of Amphiphilic Collagen for Dual Separation of Emulsions.

Industrial manufacture generates a huge quantity of emulsion wastewater, which causes serious threats to the aquatic ecosystems. Water-in-oil (W/O) and oil-in-water (O/W) emulsions are two major types of emulsions discharged by industries. However, dual separation of W/O and O/W emulsions remains a challenging issue due to the contradictory permselectivity for separating the two emulsions.

Zeolitic imidazolate framework-8 templated synthesis of a heterogeneous Pd catalyst for remediation of chlorophenols pollution.

Herein, a heterogeneous Pd catalyst was prepared by embedding Pd nanoparticles in a highly porous nitrogen-doped mesoporous carbon (NMCs) synthesized by the ZIF-8 template. The as-prepared Pd/NMC catalyst was efficient and recyclable in mild catalytic hydrodechlorination of 4-chlorophenol, 2,4-dichlorophenol and 2,4,6-trichlorophenol, showing superior performances to those of the activated carbon-supported Pd commercial catalysts.

Encapsulating NiCoO inside metal-organic framework sandwiched graphene oxide 2D composite nanosheets for high-performance lithium-ion batteries.

Ternary transition metal oxides are promising candidates for developing high-performance lithium-ion batteries. In the present investigation, we explored sandwiched composite nanosheets by encapsulating NiCo2O4 nanoparticles inside the pores of ZIF-67 crystals that were in situ grown on both surfaces of graphene oxide (GO). SEM and TEM observations confirmed the successful construction of the sophisticated architecture.

Recyclable Amphiphilic Metal Nanoparticle Colloid Enabled Atmospheric Oxidation of Alcohols.

Developing amphiphilic colloid catalysts is essentially important for realizing environmentally benign biphasic catalysis under atmospheric conditions. Herein, a linear structured plant polyphenol was employed as an amphiphilic stabilizer for preparing a series of amphiphilic Pd nanoparticles (PdNPs) colloids. For the as-prepared PdNPs colloids, the phenolic hydroxyls of plant polyphenols were responsible for the stabilization of PdNPs, whereas the rigid aromatic scaffold of plant polyphenols effectively suppressed the PdNPs from aggregation by providing a high steric effect.