Morphology controlled fabrication and ferroelectric properties of vertically aligned one-dimensional lead titanate nanoarrays.

Vertically aligned nanowires and highly uniform nanoporous array thin films of PbTiO(3) are synthesized by varying anodic oxidation conditions of Ti foil followed by hydrothermal reaction in an aqueous Pb(II) acetate trihydrate solution. As-synthesized samples have single crystalline nanowire structure and polycrystalline nanoporous structure, although both are pure PbTiO(3) with a tetragonal phase. The structure of intermediate TiO(2) films obtained from different anodic oxidation conditions determines the structure of the product PbTiO(3).

Growth of single crystalline barium titanate nanowires from TiO2 seeds deposited on conducting glass.

A new synthetic method is reported for depositing BaTiO(3) nanowire film on conducting glass. First, a TiO(2) particle thin film is prepared by spray coating, and then transformed to single crystalline BaTiO(3) nanowires grown on the conducting glass by hydrothermal treatment using TiO(2) particles as seeds of nanowire growth. The BaTiO(3) nanowires are 50-100 nm in diameter and have a film thickness of 4 µm.