The alarming state of Central Chile's groundwater resources: A paradigmatic case of a lasting overexploitation.

Ensuring water supply under climate change scenarios is a global concern, and groundwater resources play a crucial role. Aquifer depletion is a worldwide trend, and Chile is no exception. Through a statistical approach with strong hydrogeological criteria, the groundwater overexploitation phenomenon is studied in Central Chile, the most populated region in this mountainous country.

Deciphering groundwater flow-paths in fault-controlled semiarid mountain front zones (Central Chile).

The Mountain-Block Recharge (MBR), also referred to as the hidden recharge, consists of groundwater inflows from the mountain block into adjacent alluvial aquifers. This is a significant recharge process in arid environments, but frequently discarded since it is imperceptible from the ground surface. In fault-controlled Mountain Front Zones (MFZs), the hydrogeological limit between the mountain-block and adjacent alluvial basins is complex and, consequently, the groundwater flow-paths reflect that setting.

Integration of LC/MS-based molecular networking and classical phytochemical approach allows in-depth annotation of the metabolome of non-model organisms - The case study of the brown seaweed Taonia atomaria.

Untargeted LC-MS based metabolomics is a useful approach in many research areas such as medicine, systems biology, environmental sciences or even ecology. In such an approach, annotation of metabolomes of non-model organisms remains a significant challenge. In this study, an analytical workflow combining a classical phytochemical approach, using the isolation and the full characterization of the chemical structure of natural products, together with the use of MS/MS-based molecular networking with various levels of restrictiveness was developed.

Groundwater resources and recharge processes in the Western Andean Front of Central Chile.

In Central Chile, the increment of withdrawals together with drought conditions has exposed the poor understanding of the regional hydrogeological system. In this study, we addressed the Western Andean Front hydrogeology by hydrogeochemical and water stable isotope analyses of 23 springs, 10 boreholes, 5 rain-collectors and 5 leaching-rocks samples at Aconcagua Basin. From the upstream to the downstream parts of the Western Andean Front, most groundwater is HCO-Ca and results from the dissolution of anorthite, labradorite and other silicate minerals.

Humic-like acids from hydrochars: Study of the metal complexation properties compared with humic acids from anthropogenic soils using PARAFAC and time-resolved fluorescence.

Humic acids (HA) play an important role in the distribution, toxicity, and bioavailability of metals in the environment. Humic-like acids (HLA) that simulate geochemical processes can be prepared by NaOH aqueous extraction from hydrochars produced by hydrothermal carbonization (HTC). HLA can exhibit properties such as those found in HA from soils, which are known for their ability to interact with inorganic and organic compounds.