High-pressure behavior of hydrophobically coated gold nanoparticle supercrystals: role of the structure.

We report here an extensive high pressure small-angle X-ray scattering study on 3D supercrystals self-assembled from colloidal spherical gold crystalline nanoparticule (NPs). We used a large variety of NPs with different gold core diameter, from 2 to 10 nm, grafted with different ligands: alkane-thiols or oleylamine. The self assembly of these various NPs leads to supercrystals of different structures: face centered cubic (FCC), body centered cubic (BCC), as well as the C14 Frank and Kasper phase.

Mechanics under pressure of gold nanoparticle supracrystals: the role of the soft matrix.

We report on High Pressure Small Angle X-ray Scattering (HP-SAXS) measurements on 3D face-centered cubic (FCC) supracrystals (SCs) built from spherical gold nanoparticles (NPs). Dodecane-thiol ligands are grafted on the surface and ensure the stability of the gold NPs by forming a protective soft layer. Under a hydrostatic pressure of up to 12 GPa, the SC showed a high structural stability.

Precise size control of hydrophobic gold nanoparticles in the 2-5 nm range.

We report a seed-mediated synthesis strategy to control the size of gold nanoparticles at the atomic scale in the 2-5 nm size range. Starting from 2 nm seeds, a regrowth in organic solvent with a designed amount of precursor can achieve in a predictive fashion a precise mean size with a 0.3 nm resolution.

Softness-driven complexity in supercrystals of gold nanoparticles.

Many soft matter systems are composed of roughly spherical objects that can self-assemble in ordered structures. Unlike hard spheres, at high volume fraction these soft spheres adapt their shape to the local geometrical constraints and the question of space filling needs to be entirely revisited. Hydrophobically coated gold nanocrystals self-assemble in supercrystals and are good candidates to explore this question.