Pharmaceuticals and personal care products (PPCPs) monitoring in surface water is crucial to address the escalating threat of antimicrobial resistance and safeguard public health. This study aimed to investigate the occurrence of 21 different PPCPs, including wastewater chemical markers, antibiotics, and parabens in the surface water of Chennai city using Ultra Performance Liquid Chromatography-Triple Quadrupole Mass Spectrometry (UPLC-MS/MS) analysis. It is noteworthy that chemical markers viz.
View Article and Find Full Text PDFThe inclusion of ruthenium (Ru) to decorate nickel sulphide (Ru@NiS/Ni foam) resulted in a highly efficient electrocatalyst for the alkaline HER by enhancing water dissociation at the interface and reducing the energy barrier of the Volmer step. This strategic fusion significantly boosts the catalyst's performance in facilitating hydrogen production.
View Article and Find Full Text PDFThe photocatalytic production of hydrogen (H) from water is a vital avenue towards sustainable energy and addressing global environmental challenges. To maximize efficiency, harnessing the synergistic effects of multiple co-catalysts is essential, as these interactions can significantly enhance performance. In this study, we introduce a ternary heterojunction composed of a nickel-imidazole framework (Ni-MOF), graphitic carbon nitride (CN), and TiC MXene (TC), employing solvothermal and wet impregnation methods, featuring a well-designed Type II heterojunction and a noble metal-free Schottky junction for efficient hydrogen evolution.
View Article and Find Full Text PDFIn this study, we present an in situ solvothermal approach for synthesizing a highly efficient bifunctional CuBiO/BiO composite catalyst for applications in H production and the removal of organic pollutants. Various characterization techniques, including XRD, UV-vis DRS, SEM, TEM, and EIS, were used to characterize the prepared catalyst. Density functional theory calculations confirmed a Z-scheme mechanism, revealing the charge transfer mechanism from the BiO surface to the CuBiO surface.
View Article and Find Full Text PDFMetal-Organic Frameworks (MOFs) are extensively used as electrode material in various sensing applications due to their efficacious porous nature and tunable properties. However, pristine MOFs lack conductive attributes that hinder their wide usage in electrochemical applications. Electropolymerization of several aromatic monomers has been a widely used strategy for preparing conducting electrode materials for various sensing applications in the past decades.
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