The coordination of tridentate ligands featuring lateral coordination sites prone to acting as bridging ligands was explored with the aim of obtaining original polymetallic species in a straightforward and controlled manner. Accordingly, the 2-indenylidene chloropalladate [{Ind(Ph(2)P═S)(2)}PdCl](-) was found to behave as a κ(2)-C,S bidentate ligand toward metal fragments, giving access to homo- and heteropolymetallic complexes. X-ray diffraction analyses reveal the presence of short metal-metal contacts in all of these complexes.
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